Studies on Co(II) Thiosemicarbazone Adducts with 2-Pyridine Ethanol and 2,2´ -Bipyridyl

Abstract

The adducts of thiosemicarbazones of 2,5-dimethoxy phenyl glyoxal, 2-hydroxy-5-carboxy acetophenone and Co(II) phenyl thiosemicarbazone of resacetophenone with 2-pyridine ethanol and 2,2´-bipyridyl with the composition (CoLL´Cl₂H₂O), (CoLL"Cl₂H₂O), CoLL´ClH₂O)₂ and CoLL"Cl(H₂O)₂, where L═thiosemicarbazone and L´═ 2-py. ethanol and L"═2,2´-bipy., have been prepared. The adducts have been characterised on the basis of magnetic and spectral studies. Conductance values in DMF showed them to be non-electrolytes.