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The π-π Stacking Interaction of Azaborine and Some of its Derivatives: A Quantum Mechanical Study
Corresponding Author(s) : Bipul Bezbaruah
Asian Journal of Chemistry,
Vol. 32 No. 5 (2020): Vol 32 Issue 5
Abstract
Derivatives of azaborine viz., diazaborines, borazine and pseudoborazine, but interestingly all of them are not purely aromatic. The sequence of aromaticity of some azaborine and its derivatives were given as azaborine > diazaborine > pesudoborazine > borazine. Also they have different ring bond distances as B-B, N-N and B-N. Due to their difference in properties of aromaticity and structure, the π-π stacking interaction was also very interesting and quite different from the normal aromatic systems. Quantum mechanical, MP2 method is quite useful for determining the π-π stacking interaction in different azaborine dimers and its derivatives for eclipsed and staggered stacked conformations. Stacked models of azaborine derivatives with intermolecular rotations also shows different interaction energies.
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- E. Wiberg, Natunviss, 35, 182 (1948); https://doi.org/10.1007/BF00627385
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References
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B. Chiavarino, M.E. Crestoni, A.D. Marzio, S. Fornarini and M. Rosi, J. Am. Chem. Soc., 121, 11204 (1999); https://doi.org/10.1021/ja992220m
E.D. Jemmis and B. Kiran, Inorg. Chem., 37, 2110 (1998); https://doi.org/10.1021/ic970737y
A.S. Lisovenko and A.Y. Timoshkin, Inorg. Chem., 49, 10357 (2010); https://doi.org/10.1021/ic101081k
W.H. Fink and J.C. Richards, J. Am. Chem. Soc., 113, 3393 (1991); https://doi.org/10.1021/ja00009a026
P.R. Schleyer, H. Jiao, N.J.R.E. Hommes, V.G. Malkin and O.L. Malkina, J. Am. Chem. Soc., 119, 12669 (1997); https://doi.org/10.1021/ja9719135
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I. Fernandez and G. Frenking, Faraday Discuss., 135, 403 (2007); https://doi.org/10.1039/B606835A
R. Islas, E. Chamorro, J. Robles, T. Heine, J. Santos and G. Merino, Struct. Chem., 18, 833 (2007); https://doi.org/10.1007/s11224-007-9229-z
B. Kiran, A.K. Phukan and E.D. Jemmis, Inorg. Chem., 40, 3615 (2001); https://doi.org/10.1021/ic001394y
P.W. Fowler and E. Steiner, J. Phys. Chem. A, 101, 1409 (1997); https://doi.org/10.1021/jp9637946
A.K. Phukan, R.P. Kalagi, S.R. Gadre and E.D. Jemmis, Inorg. Chem., 43, 5824 (2004); https://doi.org/10.1021/ic049690o
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K. Jug, J. Org. Chem., 48, 1344 (1983); https://doi.org/10.1021/jo00156a038
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Z. Liu and T.B. Marder, Angew. Chem. Int. Ed., 47, 242 (2008); https://doi.org/10.1002/anie.200703535
C.W. Levy, C. Baldock, A.J. Wallace, S. Sedelnikova, R.C. Viner, J.M. Clough, A.R. Stuitje, A.R. Slabas, D.W. Rice and J.B. Rafferty, J. Mol. Biol., 309, 171 (2001); https://doi.org/10.1006/jmbi.2001.4643
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A. Stock and E. Pohland, Chem. Ber., 59, 2215 (1926); https://doi.org/10.1002/cber.19260590907
E.R. Abbey, A.N. Lamm, A.W. Baggett, L.N. Zakharov and S.-Y. Liu, J. Am. Chem. Soc., 135, 12908 (2013); https://doi.org/10.1021/ja4073436
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A.L. Pickering, G. Seeber, D.-L. Long and L. Cronin, CrystEngComm, 7, 504 (2005); https://doi.org/10.1039/B506718A
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