Kinetics of Ru(III) Catalysed Oxidation of Cyclohexanol by Bromamine-T in Hydrochloric Acid
Corresponding Author(s) : J.P.N. Singh
Asian Journal of Chemistry,
Vol. 4 No. 4 (1992): Vol 4 Issue 4
Abstract
The kinetics of Ru(III) catalysed oxidation of cyclohexanol by acidic solution of bromamine-T (BAT) have been reported. The reaction shows first-order kinetics in each of bromamine-T, cyclohexanol, H+ ions and Ru(III). Decreasing effect of chloride ions was observed. Ionic strength variation did not influence the reaction rate. Negligible effect of addition of p-toluene sulphonamide (one of the reaction products) was observed. A suitable mechanism consistent with observed kinetic results has been proposed.
Keywords
Kinetics
Ru(III)
Catalysed Oxidation
Cyclohexanol
Bromamine-T
Hydrochloric Acid
Singh, J., & Kumar Singh, R. (2010). Kinetics of Ru(III) Catalysed Oxidation of Cyclohexanol by Bromamine-T in Hydrochloric Acid . Asian Journal of Chemistry, 4(4), 823–827. Retrieved from https://asianpubs.org/index.php/ajchem/article/view/25158
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