Mechanism of Rh(III) Catalysis in Oxidation of Glutamic Acid by Alkaline Solution of Hexacyanoferrate(III)
Corresponding Author(s) : R.P. Singh
Asian Journal of Chemistry,
Vol. 4 No. 3 (1992): Vol 4 Issue 3
Abstract
Kinetics of Rh(III) catalysed hexacyanoferrate(III) oxidation of glutamic acid in alkaline medium have been studied. The reaction showed zero-order dependence on hexacyanoferrate(III) and OH– ion and first order kinetics with respect to both glutamic acid and Rh(III). Insignificant effect of variation of ionic strength of the medium was observed. A suitable mechanism consistent with kinetic data is proposed.
Keywords
Rh(III) Catalysis
Oxidation
Glutamic Acid
Alkaline Solution
Hexacyanoferrate(III)
Kumar Singh, B., & Singh, R. (2010). Mechanism of Rh(III) Catalysis in Oxidation of Glutamic Acid by Alkaline Solution of Hexacyanoferrate(III) . Asian Journal of Chemistry, 4(3), 508–510. Retrieved from https://asianpubs.org/index.php/ajchem/article/view/25089
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