Kinetics and Mechanism of Oxidation of Aliphatic and Aromatic Suphoxides by Peroxomonosulphate
Corresponding Author(s) : M. Krishna Pillay
Asian Journal of Chemistry,
Vol. 4 No. 1 (1992): Vol 4 Issue 1
Abstract
The title reaction in aqueous acetic acid shows first order dependence each on [oxidant] and [substrate]. Changes in [H+] and ionic strength have no effect on the reaction rate. The kinetic and thermodynamic parameters have been evaluated and a suitable mechanism proposed.
Keywords
Kinetics
Mechanism
Oxidation
Aliphatic
Aromatic Suphoxides
Peroxomonosulphate
(1)
Janakiram, T.; Maruthamuthu, P.; Krishna Pillay, M. Kinetics and Mechanism of Oxidation of Aliphatic and Aromatic Suphoxides by Peroxomonosulphate . ajc 2010, 4, 171-175.
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