Kinetics and Mechanism of Oxidation of Aliphatic and Aromatic Suphoxides by Peroxomonosulphate

T. Janakiram; P. Maruthamuthu; M. Krishna Pillay

Issue

Vol. 4 No. 1 (1992): Vol 4 Issue 1

Issue Published : January 4, 1992

Kinetics and Mechanism of Oxidation of Aliphatic and Aromatic Suphoxides by Peroxomonosulphate

T. Janakiram

Department of Chemistry, Bharathidasan University, Tiruchirapalli-620 024, India

P. Maruthamuthu

Department of Chemistry, Bharathidasan University, Tiruchirapalli-620 024, India

M. Krishna Pillay

Department of Chemistry, Bharathidasan University, Tiruchirapalli-620 024, India

Corresponding Author(s) : M. Krishna Pillay

Asian Journal of Chemistry, Vol. 4 No. 1 (1992): Vol 4 Issue 1
Article Published : March 30, 2010

Abstract

The title reaction in aqueous acetic acid shows first order dependence each on [oxidant] and [substrate]. Changes in [H+] and ionic strength have no effect on the reaction rate. The kinetic and thermodynamic parameters have been evaluated and a suitable mechanism proposed.

Keywords

Kinetics Mechanism Oxidation Aliphatic Aromatic Suphoxides Peroxomonosulphate

Janakiram, T., Maruthamuthu, P., & Krishna Pillay, M. (2010). Kinetics and Mechanism of Oxidation of Aliphatic and Aromatic Suphoxides by Peroxomonosulphate . Asian Journal of Chemistry, 4(1), 171–175. Retrieved from https://asianpubs.org/index.php/ajchem/article/view/25018

Issue

Vol. 4 No. 1 (1992): Vol 4 Issue 1

Kinetics and Mechanism of Oxidation of Aliphatic and Aromatic Suphoxides by Peroxomonosulphate

Corresponding Author(s) : M. Krishna Pillay

Abstract

Keywords

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