Copyright (c) 2020 AJC
This work is licensed under a Creative Commons Attribution 4.0 International License.
Citrus sinensis Seed as a Potential Source of Quality Edible and Industrial Oil
Corresponding Author(s) : Victor Y.A. Barku
Asian Journal of Chemistry,
Vol. 32 No. 5 (2020): Vol 32 Issue 5
Abstract
Seeds of sweet oranges (Citrus sinensis) were analyzed for oil and fatty acid composition. The crude oil was extracted by the use of soxhlet extraction. The results showed that oil content is as high as 71 %. The physico-chemical assessment gave the following results: refractive index (1.457), peroxide value (4.12 meq/kg) and iodine value (34.06 Wijs). The ATR-IR spectrum of oil showed prominent bands at 3008.6, 2921.73, 2852.7, 1742.86, 1709.23, 1460, 1167.66, 1117.39 and 1051.16 cm-1 that identified fatty acid composition. The percentage compositions of various classes of fatty acids present in the oil were polyunsaturated fatty acids (PUFAs, 39.82 %), monounsaturated fatty acids (MUFAs, 57.08 %) and saturated fatty acids (SFAs, 3.09 %). The oil has linoleic acid (18:2, n-6) as the only PUFA and the second highest fatty acid composition (25.63 %). Palmitoleic acid is the highest MUFA (56.30 %) as well as the highest fatty acid composition while capric acid (C10:0) is the lowest fatty acid (0.02 %). These results and in addition to the low compositions of erucic acid, behenic acid and lignoceric acid indicated that the seed oil of sweet orange is possible suitable for both human consumption and industrial purposes.
Keywords
Download Citation
Endnote/Zotero/Mendeley (RIS)BibTeX
- C.E. Housecroft and E.C. Constable, Chemistry: An Introduction to Organic, Inorganic and Physical Chemistry, Pearson Education Limited: Harlow, England, pp. 1300-1304 (2010).
- F. Anwar, R. Naseer, M.I. Bhanger, S. Ashraf, F.N. Talpur and F.A. Aladedunye, J. Am. Oil Chem. Soc., 85, 321 (2008); https://doi.org/10.1007/s11746-008-1204-3
- C. Dhuique-Mayer, C. Caris-Veyrat, P. Ollitrault, F. Curk and M.-J. Amiot, J. Agric. Food Chem., 53, 2140 (2005); https://doi.org/10.1021/jf0402983
- A. Abubakar, S. Ibrahim and F.I. Musa, Int. J. Bioeng. Life Sci., 8, 1174 (2014).
- I.A.A. Ibrahim and A.J. Yusuf, Eur. J. Exp. Biol., 5, 77 (2015).
- I. Tarhan, A.A. Ismail and H. Kara, Int. J. Food Prop., 20(Supp1.), S790 (2017); https://doi.org/10.1080/10942912.2017.1312437
- J.A.O. Oyekunle and A.A. Omode, Int. J. Food Prop., 11, 273 (2008); https://doi.org/10.1080/10942910701302598
- E.I. Adeyeye and A.J. Adesina, Int. J. Curr. Microbiol. Appl. Sci., 4, 537 (2015).
- B.E. Nwobi, O.O. Ofoegbu and O.B. Adesina, Afr. J. Food Agric. Nutr. Dev., 6, 1 (2006).
- A. Waheed, S. Mahmud, M. Saleem and T. Ahmad, J. Saudi Chem. Soc., 13, 269 (2009); https://doi.org/10.1016/j.jscs.2009.10.007
- V. Hernández-Montoya, M.A. Montes-Morán and M.P. ElizaldeGonzález, Biomass Bioenergy, 33, 1295 (2009); https://doi.org/10.1016/j.biombioe.2009.05.016
- B. Matthäus, Food Science, Technology and Nutrition, Woodhead Publishing Series, pp. 183-238, (2010).
- F. Kong and R.P. Singh, Food Science, Technology and Nutrition, Woodhead Publishing Series, pp. 381-404 (2011).
- S.V. Omosuli, J. Food Dairy Technol., 2, 5 (2014).
- T.H. Sanders, Encyclopedia of Food Sciences and Nutrition, Academic Press, USA, pp. 2967-2974, (2003).
- B.A. Orhevba, O. Chukwu, V. Oguagwu and Z.D. Osunde, Int. J. Eng. Sci., 2, 1 (2013).
- E.C. Enyoh, C.E. Enyoh and C.E. Amaobi, World Sci. News, 88, 152 (2017).
- C.P.M. Aranha and N. Jorge, Food Sci. Technol. Res., 19, 409 (2013); https://doi.org/10.3136/fstr.19.409
- J. Orsavova, L. Misurcova, J.V. Ambrozova, R. Vicha and J. Mlcek, Int. J. Mol. Sci., 16, 12871 (2015); https://doi.org/10.3390/ijms160612871
- Y. Shara, M.M. Majidi, S.A.H. Goli and F. Rashidi, Int. J. Food Prop., 18, 2145 (2015); https://doi.org/10.1080/10942912.2014.968284
- Food Standards Australia New Zealand, Technical Report Series no. 21, (2003).
- C.C. Akoh and D.B. Min, Food Lipids: Chemistry, Nutrition and Biotechnology, CRC Press: Boca Raton (2008).
- K. Chow-Ching, Fatty Acids in Foods and their Health Implication, CRC Press: Boca Raton (2007).
- Z.-H. Yang, H. Miyahara and A. Hatanaka, Lipids Health Dis., 10, 120 (2011); https://doi.org/10.1186/1476-511X-10-120
- N.G. Morgan and S. Dhayal, Prostagland. Leukot. Essent. Fatty Acids, 82, 231 (2010); https://doi.org/10.1016/j.plefa.2010.02.018
- G. Pennick, B. Chavan, B. Summers and A.V. Rawlings, Int. J. Cosmet. Sci., 34, 567 (2012); https://doi.org/10.1111/j.1468-2494.2012.00749.x
- A. Mancini, E. Imperlini, E. Nigro, C. Montagnese, A. Daniele, S. Orrù and P. Buono, Molecules, 20, 17339 (2015); https://doi.org/10.3390/molecules200917339
References
C.E. Housecroft and E.C. Constable, Chemistry: An Introduction to Organic, Inorganic and Physical Chemistry, Pearson Education Limited: Harlow, England, pp. 1300-1304 (2010).
F. Anwar, R. Naseer, M.I. Bhanger, S. Ashraf, F.N. Talpur and F.A. Aladedunye, J. Am. Oil Chem. Soc., 85, 321 (2008); https://doi.org/10.1007/s11746-008-1204-3
C. Dhuique-Mayer, C. Caris-Veyrat, P. Ollitrault, F. Curk and M.-J. Amiot, J. Agric. Food Chem., 53, 2140 (2005); https://doi.org/10.1021/jf0402983
A. Abubakar, S. Ibrahim and F.I. Musa, Int. J. Bioeng. Life Sci., 8, 1174 (2014).
I.A.A. Ibrahim and A.J. Yusuf, Eur. J. Exp. Biol., 5, 77 (2015).
I. Tarhan, A.A. Ismail and H. Kara, Int. J. Food Prop., 20(Supp1.), S790 (2017); https://doi.org/10.1080/10942912.2017.1312437
J.A.O. Oyekunle and A.A. Omode, Int. J. Food Prop., 11, 273 (2008); https://doi.org/10.1080/10942910701302598
E.I. Adeyeye and A.J. Adesina, Int. J. Curr. Microbiol. Appl. Sci., 4, 537 (2015).
B.E. Nwobi, O.O. Ofoegbu and O.B. Adesina, Afr. J. Food Agric. Nutr. Dev., 6, 1 (2006).
A. Waheed, S. Mahmud, M. Saleem and T. Ahmad, J. Saudi Chem. Soc., 13, 269 (2009); https://doi.org/10.1016/j.jscs.2009.10.007
V. Hernández-Montoya, M.A. Montes-Morán and M.P. ElizaldeGonzález, Biomass Bioenergy, 33, 1295 (2009); https://doi.org/10.1016/j.biombioe.2009.05.016
B. Matthäus, Food Science, Technology and Nutrition, Woodhead Publishing Series, pp. 183-238, (2010).
F. Kong and R.P. Singh, Food Science, Technology and Nutrition, Woodhead Publishing Series, pp. 381-404 (2011).
S.V. Omosuli, J. Food Dairy Technol., 2, 5 (2014).
T.H. Sanders, Encyclopedia of Food Sciences and Nutrition, Academic Press, USA, pp. 2967-2974, (2003).
B.A. Orhevba, O. Chukwu, V. Oguagwu and Z.D. Osunde, Int. J. Eng. Sci., 2, 1 (2013).
E.C. Enyoh, C.E. Enyoh and C.E. Amaobi, World Sci. News, 88, 152 (2017).
C.P.M. Aranha and N. Jorge, Food Sci. Technol. Res., 19, 409 (2013); https://doi.org/10.3136/fstr.19.409
J. Orsavova, L. Misurcova, J.V. Ambrozova, R. Vicha and J. Mlcek, Int. J. Mol. Sci., 16, 12871 (2015); https://doi.org/10.3390/ijms160612871
Y. Shara, M.M. Majidi, S.A.H. Goli and F. Rashidi, Int. J. Food Prop., 18, 2145 (2015); https://doi.org/10.1080/10942912.2014.968284
Food Standards Australia New Zealand, Technical Report Series no. 21, (2003).
C.C. Akoh and D.B. Min, Food Lipids: Chemistry, Nutrition and Biotechnology, CRC Press: Boca Raton (2008).
K. Chow-Ching, Fatty Acids in Foods and their Health Implication, CRC Press: Boca Raton (2007).
Z.-H. Yang, H. Miyahara and A. Hatanaka, Lipids Health Dis., 10, 120 (2011); https://doi.org/10.1186/1476-511X-10-120
N.G. Morgan and S. Dhayal, Prostagland. Leukot. Essent. Fatty Acids, 82, 231 (2010); https://doi.org/10.1016/j.plefa.2010.02.018
G. Pennick, B. Chavan, B. Summers and A.V. Rawlings, Int. J. Cosmet. Sci., 34, 567 (2012); https://doi.org/10.1111/j.1468-2494.2012.00749.x
A. Mancini, E. Imperlini, E. Nigro, C. Montagnese, A. Daniele, S. Orrù and P. Buono, Molecules, 20, 17339 (2015); https://doi.org/10.3390/molecules200917339