Template Synthesis of Oxozirconium(IV) Complexes with Tetraaza 16- and 18-Membered Macrocyclic Ligand
Corresponding Author(s) : H.S. Yadav
Asian Journal of Chemistry,
Vol. 5 No. 2 (1993): Vol 5 Issue 2
Abstract
The macrocylic complexes of types [ZrO(mac)H2O]Cl2 or [Zr(OH)2(mac)]Cl2 (where mac = macrocyclic ligands derived by condensation of diamines with β-diketones) have been synthesized by an in situ method where the metal cation acts as a template. The isolated complexes have been characterized on the basis of elemental analyses, electrical conductance and infarared spectral data. The oxozirconium(IV) complexes are six-coordinate. The tetraaza macrocyclic ligands are coordinated to the metal ion through four azomethine nitrogen atoms.
Keywords
Template Synthesis
Oxozirconium(IV) Complex
Tetraaza16- and 18-Membered
Macrocyclic Ligand
(1)
Yadav, H. Template Synthesis of Oxozirconium(IV) Complexes With Tetraaza 16- and 18-Membered Macrocyclic Ligand . ajc 2010, 5, 335-339.
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