Ir(III) Catalysis in N-Bromosuccinimide Oxidation of Lactic Acid in Perchloric Acid
Corresponding Author(s) : B.N. Singh
Asian Journal of Chemistry,
Vol. 5 No. 2 (1993): Vol 5 Issue 2
Abstract
Kinetic data on Ir(III) catalysed oxidation of lactic acid (LA) by N-bromosuccinimide (NBS) in perchloric acid in the presence of mercuric acetate as scavenger show first-order in each NBS, LA and Ir(III) and zero-order in [H+]. Negative effect of succinimide, positive effect of chloride ions and zero effect of ionic strength have been observed. Mechanistic steps are discussed.
Keywords
Ir(III) Catalysis
N-Bromosuccinimide Oxidation
Lactic Acid
Perchloric Acid
Singh, B., Prasad, A., & Singh, S. (2010). Ir(III) Catalysis in N-Bromosuccinimide Oxidation of Lactic Acid in Perchloric Acid . Asian Journal of Chemistry, 5(2), 327–329. Retrieved from https://asianpubs.org/index.php/ajchem/article/view/24812
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