Issue

Vol. 32 No. 3 (2020): Vol 32 Issue 3

Copyright (c) 2020 AJC

Creative Commons License

This work is licensed under a Creative Commons Attribution 4.0 International License.

Synthesis, XRD, EXAFS and XANES Study of Cu(II) Complexes of Aniline Dithiocarbamate

https://doi.org/10.14233/ajchem.2020.22456%20
Anurag Geete
Department of Physics, Shri Rewa Gurjar Bal Niketan College, Sanawad, Khargone-451111, India
B.D. Shrivastava
Department of Physics, Maharaja Bhoj Government P.G. College, Dhar-454001, India
Ashutosh Mishra
School of Physics, Devi Ahilya University, Indore-452001, India

Corresponding Author(s) : Anurag Geete

anuraggeete.21@gmail.com

Asian Journal of Chemistry, Vol. 32 No. 3 (2020): Vol 32 Issue 3

Abstract

In present investigation, seven copper(II) complexes were synthesized using various aniline dithiocarbamate. The synthesized Cu(II) complexes were studied for different structural and chemical parameters using XRD, EXAFS and XANES. The output obtained from X-ray studies was synthesized using Athena and Origin 6.0 software. The results of the investigation were used in determining the structures of the synthesized complexes. The particle size of the synthesized complexes ranged between 46.7 and 125.3 nm. The lattice constant of Cu(II) complexes was found 3.61-3.62 Å.

Keywords

Aniline dithiocarbamate Cu(II) complex EXAFS Ligands XRD XANES
Geete, A., Shrivastava, B., & Mishra, A. (2020). Synthesis, XRD, EXAFS and XANES Study of Cu(II) Complexes of Aniline Dithiocarbamate. Asian Journal of Chemistry, 32(3), 627–633. https://doi.org/10.14233/ajchem.2020.22456
Download Citation
Endnote/Zotero/Mendeley (RIS)
BibTeX
References
  1. J. Meija, T.B. Coplen, M. Berglund, W.A. Brand, P. De Bièvre, M. Gröning, N.E. Holden, J. Irrgeher, R.D. Loss, T. Walczyk and T. Prohaska, Pure Appl. Chem., 88, 265 (2016); https://doi.org/10.1515/pac-2015-0305
  2. F. William, H.J. Smith and F. Presuel-Moreno, Foundations of Materials Science and Engineering, McGraw-Hill Publishing, edn 5 (2006).
  3. R.B. Gordon, M. Bertram and T.E. Graedel, Proc. Natl. Acad. Sci. USA, 103, 1209 (2006); https://doi.org/10.1073/pnas.0509498103
  4. N. Krause, Modern Organocopper Chemistry, John Wiley & Sons (2002).
  5. R. Chinchilla and C. Nájera, Chem. Rev., 107, 874 (2007); https://doi.org/10.1021/cr050992x.
  6. T.C. Pleger, Proceedings of Twenty-Seventh Annual Meeting of the Forest History Association of Wisconsin, Oconto, WI, vol. 5, pp. 10-18 (2002).
  7. N.K. Kaushik, B. Bhushan and A.K. Sharma, Transition Met. Chem., 9, 250 (1984); https://doi.org/10.1007/BF00624466
  8. A.T. Odularu and P.A. Ajibade, 2019, Article ID 8260496 (2019); https://doi.org/10.1155/2019/8260496
  9. V. Milacic, D. Chen, L. Ronconi and K.R.L. Piwowar, D. Fregona and Q.P. Dou, Cancer Res., 66, 10478 (2006); https://doi.org/10.1158/0008-5472.CAN-06-3017
  10. A.J. Blake, L.M. Gilby, R.O. Gould, V. Lippolis, S. Parsons and M. Schröder, Acta Crystallogr., C54, 295 (1998); https://doi.org/10.1107/S0108270197014212
  11. B. Kersting, Z. Naturforschung B, 55, 961 (2000); https://doi.org/10.1515/znb-2000-1012
  12. I. Gürol, V. Ahsen and Ö. Bekâroglu, J. Chem. Soc., Dalton Trans., 2283 (1992); https://doi.org/10.1039/DT9920002283
  13. Z.H. Chohan, M. Praveen and A. Ghaffaf, Inorg. Met.-Org. Chem., 28, 1673 (1998); https://doi.org/10.1080/00945719809349422.
  14. B.B. Kaul and K.B. Pandeya, J. Inorg. Nucl. Chem., 43, 1942 (1981); https://doi.org/10.1016/0022-1902(81)80419-8
  15. A. Mishra, A. Yadav, S. Ninama and A. Trivedi, J. Phys. Conf. Ser., 365, 1 (2012).
  16. S. Mohammad, A. Mishra, P. Sharma and S. Patidar, Int. J. Scient. Res. Phy. Appl. Sci., 6, 1 (2018).
  17. A. Geete, B.D. Shrivastava, A. Mishra and N. Parsai, Int. J. Scient. Res. Rev., 7, 1030 (2019).
Read More
Author biographies is not available.
Download
PDF
Statistic
Read Counter : 0 Download : 0