Copyright (c) 2020 AJC
This work is licensed under a Creative Commons Attribution 4.0 International License.
Synthesis of Ag@Polycarbazole Nanocomposite using Ferric Acetate as an Oxidant
Corresponding Author(s) : Mohamad Nasir Mohamad Ibrahim
Asian Journal of Chemistry,
Vol. 32 No. 5 (2020): Vol 32 Issue 5
Abstract
Silver nanowires and Ag@polycarbazole nanocables have been effectively fabricated. Polyol-reduction and ion adsorption process were used to fabricate pure silver nanowires and Ag@polycarbazole nanocomposite by using an oxidant (iron acetate). Ions of oxidant were adsorbed on the surface of pure silver nanowires to oxidize carbazole monomers for efficient polymerization. The morphology of nanowires and Ag@PCz composite were characterized by using SEM, FT-IR and photoluminescence analysis. The SEM shows the presence of a smooth polymeric sheath. FT-IR and photoluminescence analysis shows dominant peaks that indicate the presence of silver nanowires and polycarbazole (PCz) with a smooth polymeric coating. Nanoparticle analyzer was used to determine z-average and actual size of sample. UV-visible spectrum shows two bands that were dominant at 345 and 410 nm. These are π to π* transitions that indicates the presence of polycarbazole nanocables.
Keywords
Download Citation
Endnote/Zotero/Mendeley (RIS)BibTeX
- F. Faupel, V. Zaporojtchenko, T. Strunskus and M. Elbahri, Adv. Eng. Mater., 12, 1177 (2010); https://doi.org/10.1002/adem.201000231
- J. Du, J. Bai and H. Cheng, Express Polym. Lett., 1, 253 (2007); https://doi.org/10.3144/expresspolymlett.2007.39
- A. Rahman, I. Ali, S.M. Al Zahrani and R.H. Eleithy, Nano, 6, 185 (2011); https://doi.org/10.1142/S179329201100255X
- R.M. Mutiso and K.I. Winey, Prog. Polym. Sci., 40, 63 (2015); https://doi.org/10.1016/j.progpolymsci.2014.06.002
- P.S. Abthagir and R. Saraswathi, Thermochim. Acta, 424, 25 (2004); https://doi.org/10.1016/j.tca.2004.04.028
- A. Matoliukstyte, E. Burbulis, J.V. Grazulevicius, V. Gaidelis and V. Jankauskas, Synth. Met., 158, 462 (2008); https://doi.org/10.1016/j.synthmet.2008.03.020
- C.-J. Huang, F.-S. Shieu, W.-P. Hsieh and T.-C. Chang, J. Appl. Polym. Sci., 100, 1457 (2006); https://doi.org/10.1002/app.23576
- Z.H. Mbhele, M.G. Salemane, C.G.C.E. van Sittert, J.M. Nedeljkovic, V. Djokovic and A.S. Luyt, Chem. Mater., 15, 5019 (2003); https://doi.org/10.1021/cm034505a
- J. Feng, K.-Y. Wong, G.C. Lynch, X. Gao and B.M. Pettitt, J. Phys. Chem., 111, 13797 (2007); https://doi.org/10.1021/jp075051y
- W.Z. Teo and M. Pumera, RSC Adv., 4, 5006 (2014); https://doi.org/10.1039/c3ra43224f
- A. Shahpal, M. Aziz Choudhary and Z. Ahmad, Cogent Chem., 3, 1301241 (2017); https://doi.org/10.1080/23312009.2017.1301241
- S. Wang, C.-Y. Huang, L. Pan, Y. Chen, X. Zhang, Fazal-e-Aleem and J.-J. Zou, Catal. Today, 335, 151 (2019); https://doi.org/10.1016/j.cattod.2018.10.059
- T. Soganci, Y. Baygu, N. Kabay, Y. Gök and M. Ak, ACS Appl. Mater. Interfaces, 10, 21654 (2018); https://doi.org/10.1021/acsami.8b06206
- Q. Cao, Q. Chen and B. Han, Acta Chim. Sin., 73, 541 (2015); https://doi.org/10.6023/A15020126
- H.N. Doan, H. Tsuchida, T. Iwata, K. Kinashi, W. Sakai, N. Tsutsumi and D.P. Huynh, RSC Adv., 7, 33061 (2017); https://doi.org/10.1039/C7RA03794E
- Y. Liu, G. Zhu, J. Gao, M. Hojamberdiev, R. Zhu, X. Wei, Q. Guo and P. Liu, Appl. Catal. B, 200, 72 (2017); https://doi.org/10.1016/j.apcatb.2016.06.069
- E. Contal, C.M. Sougueh, S. Lakard, A. Et Taouil, C. Magnenet and B. Lakard, Frontiers Mater., 6, 131 (2019); https://doi.org/10.3389/fmats.2019.00131
- R.R. da Silva, M. Yang, S.-I. Choi, M. Chi, M. Luo, C. Zhang, Z.-Y. Li, P.H.C. Camargo, S.J.L. Ribeiro and Y. Xia, ACS Nano, 10, 7892 (2010); https://doi.org/10.1021/acsnano.6b03806
- A. Zahoor, T. Qiu, J. Zhang and X. Li, J. Mater. Sci., 44, 6054 (2009); https://doi.org/10.1007/s10853-009-3831-y
- Z. Ahmad, M. Maqsood, M. Mehmood, M.J. Ahmad and M.A. Choudhary, Bull. Chem. React. Eng. Catal., 12, 127 (2017); https://doi.org/10.9767/bcrec.12.1.860.127-135
- Z. Ahmad, A. Afreen, M. Mehmood, I. Ali, R. Asgher and M. Aziz, J. Nanostruc. Chem., 5, 325 (2015); https://doi.org/10.1007/s40097-015-0164-z
- A.H. Chen, H.X. Xie, H.Q. Wang, H.Y. Li and X. Li, Synth. Met., 156, 346 (2006); https://doi.org/10.1016/j.synthmet.2005.12.017
- M. Ates and N. Uludag, J. Solid State Electrochem., 20, 2599 (2016); https://doi.org/10.1007/s10008-016-3269-5
- A.S. Sarac, S.A.M. Tofail, M. Serantoni, J. Henry, V.J. Cunnane and J.B. McMonagle, Appl. Surf. Sci., 222, 148 (2004); https://doi.org/10.1016/j.apsusc.2003.08.008
- T. Miyazaki, S.-K. Kim and K. Hoshino, Chem. Mater., 18, 5302 (2006); https://doi.org/10.1021/cm060613w
- T. Qiu, H. Xie, J. Zhang, A. Zahoor and X. Li, J. Nanopart. Res., 13, 1175 (2011); https://doi.org/10.1007/s11051-010-0109-x
- J. Xu, X. Han, H. Liu and Y. Hu, Colloids Surf. A Physicochem. Eng. Asp., 273, 179 (2006); https://doi.org/10.1016/j.colsurfa.2005.08.019
References
F. Faupel, V. Zaporojtchenko, T. Strunskus and M. Elbahri, Adv. Eng. Mater., 12, 1177 (2010); https://doi.org/10.1002/adem.201000231
J. Du, J. Bai and H. Cheng, Express Polym. Lett., 1, 253 (2007); https://doi.org/10.3144/expresspolymlett.2007.39
A. Rahman, I. Ali, S.M. Al Zahrani and R.H. Eleithy, Nano, 6, 185 (2011); https://doi.org/10.1142/S179329201100255X
R.M. Mutiso and K.I. Winey, Prog. Polym. Sci., 40, 63 (2015); https://doi.org/10.1016/j.progpolymsci.2014.06.002
P.S. Abthagir and R. Saraswathi, Thermochim. Acta, 424, 25 (2004); https://doi.org/10.1016/j.tca.2004.04.028
A. Matoliukstyte, E. Burbulis, J.V. Grazulevicius, V. Gaidelis and V. Jankauskas, Synth. Met., 158, 462 (2008); https://doi.org/10.1016/j.synthmet.2008.03.020
C.-J. Huang, F.-S. Shieu, W.-P. Hsieh and T.-C. Chang, J. Appl. Polym. Sci., 100, 1457 (2006); https://doi.org/10.1002/app.23576
Z.H. Mbhele, M.G. Salemane, C.G.C.E. van Sittert, J.M. Nedeljkovic, V. Djokovic and A.S. Luyt, Chem. Mater., 15, 5019 (2003); https://doi.org/10.1021/cm034505a
J. Feng, K.-Y. Wong, G.C. Lynch, X. Gao and B.M. Pettitt, J. Phys. Chem., 111, 13797 (2007); https://doi.org/10.1021/jp075051y
W.Z. Teo and M. Pumera, RSC Adv., 4, 5006 (2014); https://doi.org/10.1039/c3ra43224f
A. Shahpal, M. Aziz Choudhary and Z. Ahmad, Cogent Chem., 3, 1301241 (2017); https://doi.org/10.1080/23312009.2017.1301241
S. Wang, C.-Y. Huang, L. Pan, Y. Chen, X. Zhang, Fazal-e-Aleem and J.-J. Zou, Catal. Today, 335, 151 (2019); https://doi.org/10.1016/j.cattod.2018.10.059
T. Soganci, Y. Baygu, N. Kabay, Y. Gök and M. Ak, ACS Appl. Mater. Interfaces, 10, 21654 (2018); https://doi.org/10.1021/acsami.8b06206
Q. Cao, Q. Chen and B. Han, Acta Chim. Sin., 73, 541 (2015); https://doi.org/10.6023/A15020126
H.N. Doan, H. Tsuchida, T. Iwata, K. Kinashi, W. Sakai, N. Tsutsumi and D.P. Huynh, RSC Adv., 7, 33061 (2017); https://doi.org/10.1039/C7RA03794E
Y. Liu, G. Zhu, J. Gao, M. Hojamberdiev, R. Zhu, X. Wei, Q. Guo and P. Liu, Appl. Catal. B, 200, 72 (2017); https://doi.org/10.1016/j.apcatb.2016.06.069
E. Contal, C.M. Sougueh, S. Lakard, A. Et Taouil, C. Magnenet and B. Lakard, Frontiers Mater., 6, 131 (2019); https://doi.org/10.3389/fmats.2019.00131
R.R. da Silva, M. Yang, S.-I. Choi, M. Chi, M. Luo, C. Zhang, Z.-Y. Li, P.H.C. Camargo, S.J.L. Ribeiro and Y. Xia, ACS Nano, 10, 7892 (2010); https://doi.org/10.1021/acsnano.6b03806
A. Zahoor, T. Qiu, J. Zhang and X. Li, J. Mater. Sci., 44, 6054 (2009); https://doi.org/10.1007/s10853-009-3831-y
Z. Ahmad, M. Maqsood, M. Mehmood, M.J. Ahmad and M.A. Choudhary, Bull. Chem. React. Eng. Catal., 12, 127 (2017); https://doi.org/10.9767/bcrec.12.1.860.127-135
Z. Ahmad, A. Afreen, M. Mehmood, I. Ali, R. Asgher and M. Aziz, J. Nanostruc. Chem., 5, 325 (2015); https://doi.org/10.1007/s40097-015-0164-z
A.H. Chen, H.X. Xie, H.Q. Wang, H.Y. Li and X. Li, Synth. Met., 156, 346 (2006); https://doi.org/10.1016/j.synthmet.2005.12.017
M. Ates and N. Uludag, J. Solid State Electrochem., 20, 2599 (2016); https://doi.org/10.1007/s10008-016-3269-5
A.S. Sarac, S.A.M. Tofail, M. Serantoni, J. Henry, V.J. Cunnane and J.B. McMonagle, Appl. Surf. Sci., 222, 148 (2004); https://doi.org/10.1016/j.apsusc.2003.08.008
T. Miyazaki, S.-K. Kim and K. Hoshino, Chem. Mater., 18, 5302 (2006); https://doi.org/10.1021/cm060613w
T. Qiu, H. Xie, J. Zhang, A. Zahoor and X. Li, J. Nanopart. Res., 13, 1175 (2011); https://doi.org/10.1007/s11051-010-0109-x
J. Xu, X. Han, H. Liu and Y. Hu, Colloids Surf. A Physicochem. Eng. Asp., 273, 179 (2006); https://doi.org/10.1016/j.colsurfa.2005.08.019