Kinetics and Mechanism of Oxidation of Substituted Benzaldehydes by Peroxydisulphate

B.L. Hiran; S.L. Jain; S.N. Joshi

Issue

Vol. 6 No. 4 (1994): Vol 6 Issue 4

Issue Published : October 28, 1994

Kinetics and Mechanism of Oxidation of Substituted Benzaldehydes by Peroxydisulphate

B.L. Hiran

Department of Chemistry ,College of Science, Sukhadia University, Udaipur-313 001, India

S.L. Jain

Department of Chemistry ,College of Science, Sukhadia University, Udaipur-313 001, India

S.N. Joshi

Department of Chemistry ,College of Science, Sukhadia University, Udaipur-313 001, India

Corresponding Author(s) : B.L. Hiran

Asian Journal of Chemistry, Vol. 6 No. 4 (1994): Vol 6 Issue 4
Article Published : March 30, 2010

Abstract

Kinetics of the oxidation of substituted benzaldehydes by peroxydisulphate have been studied. The reaction has a first order dependence on (S₂O^2–₈) concentration. The rate is independent of the Ag(I) concentration. The rate of oxidation of substrate is dependent on the concentration of substrate. Michaelis Menten type of rate dependence on the substrate has been observed. A tentative mechanism has been proposed based on experimental data.

Keywords

Kinetics Mechanism Oxidation Benzaldehydes Peroxydisulphate

Hiran, B., Jain, S., & Joshi, S. (2010). Kinetics and Mechanism of Oxidation of Substituted Benzaldehydes by Peroxydisulphate . Asian Journal of Chemistry, 6(4), 830–834. Retrieved from https://asianpubs.org/index.php/ajchem/article/view/24681

Issue

Vol. 6 No. 4 (1994): Vol 6 Issue 4

Kinetics and Mechanism of Oxidation of Substituted Benzaldehydes by Peroxydisulphate

Corresponding Author(s) : B.L. Hiran

Abstract

Keywords

Full Article

Download Citation

Table Of Contents