Kinetics of Oxidation of Triphenylarsine and Triphenylstibine by Hydrogen Peroxide
Corresponding Author(s) : A. Chellamani
Asian Journal of Chemistry,
Vol. 6 No. 4 (1994): Vol 6 Issue 4
Abstract
The kinetics of oxidation of triphenylarsine and triphenylstibine (Ph3M; M = As, Sb) have been studied in 70% (v/v) and 95% (v/v) aqueous ethanol respectively. The reaction exhibits second-order kinetics, first-order each in Ph3M and Hydrogen peroxide. A mechanism analogous t the one proposed for the oxidation of triphenylphosphine has been suggested.
Keywords
Kinetics
Oxidation
Triphenylarsine
Triphenylstibine
Hydrogen Peroxide
(1)
Chellamani, A.; Chidambaram, K. Kinetics of Oxidation of Triphenylarsine and Triphenylstibine by Hydrogen Peroxide. ajc 2012, 6, 817-820.
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