Kinetics of Oxidation of Triphenylarsine and Triphenylstibine by Hydrogen Peroxide

A. Chellamani; K.C.A.D. Chidambaram

Issue

Vol. 6 No. 4 (1994): Vol 6 Issue 4

Issue Published : October 28, 1994

Kinetics of Oxidation of Triphenylarsine and Triphenylstibine by Hydrogen Peroxide

A. Chellamani

Department of Chemistry, Manonmaniam Sundarnagar University, Tirunelveli-627 009, India

K.C.A.D. Chidambaram

Department of Chemistry, Manonmaniam Sundarnagar University, Tirunelveli-627 009, India

Corresponding Author(s) : A. Chellamani

Asian Journal of Chemistry, Vol. 6 No. 4 (1994): Vol 6 Issue 4
Article Published : July 17, 2012

Abstract

The kinetics of oxidation of triphenylarsine and triphenylstibine (Ph₃M; M = As, Sb) have been studied in 70% (v/v) and 95% (v/v) aqueous ethanol respectively. The reaction exhibits second-order kinetics, first-order each in Ph₃M and Hydrogen peroxide. A mechanism analogous t the one proposed for the oxidation of triphenylphosphine has been suggested.

Keywords

Kinetics Oxidation Triphenylarsine Triphenylstibine Hydrogen Peroxide

Chellamani, A., & Chidambaram, K. (2012). Kinetics of Oxidation of Triphenylarsine and Triphenylstibine by Hydrogen Peroxide. Asian Journal of Chemistry, 6(4), 817–820. Retrieved from https://asianpubs.org/index.php/ajchem/article/view/24680

Issue

Vol. 6 No. 4 (1994): Vol 6 Issue 4

Kinetics of Oxidation of Triphenylarsine and Triphenylstibine by Hydrogen Peroxide

Corresponding Author(s) : A. Chellamani

Abstract

Keywords

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