Kinetics and Mechanism of Ru(III) Catalysed Oxidation of Sodium Thioglycollate by Alkaline Hexacyanoferrate(III) Ion
Corresponding Author(s) : B.N. Singh
Asian Journal of Chemistry,
Vol. 6 No. 4 (1994): Vol 6 Issue 4
Abstract
Kinetic data on Ru(III) catalysed oxidation of sodium thioglycollate by alkaline solution of hexacyanoferrate(III) has been reported. The reaction follows zero-order kinetics in hexacyanoferrate(III) while first order dependence on each sodium thioglycollate, OH and Ru(III) was observed. A suitable mechanism consistent with kinetics data has been proposed.
Keywords
Kinetics
Mechanism
Ru(III)
Catalysed Oxidation
Sodium Thioglycollate
Alkaline Hexacyanoferrate(III) Ion
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Singh, B.; Singh, S.; Prasad, A. Kinetics and Mechanism of Ru(III) Catalysed Oxidation of Sodium Thioglycollate by Alkaline Hexacyanoferrate(III) Ion . ajc 2010, 6, 756-758.
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