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Vol. 32 No. 5 (2020): Vol 32 Issue 5

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Synthesis and Characterization of 1,2,3-Triazole Containing Fe(II) Sensor

G. Senthilkumaran
Department of Chemistry, Government Arts College (Autonomous), Salem-636007, India
S. Senthil
Department of Chemistry, Government Arts College (Autonomous), Salem-636007, India

Corresponding Author(s) : S. Senthil

shendils@gmail.com

Asian Journal of Chemistry, Vol. 32 No. 5 (2020): Vol 32 Issue 5

Abstract

A new bis(1,2,3-triazolyl) imine based probe was designed and synthesized. Chemical structure of the probe was confirmed by IR, 1H and 13C NMR spectroscopy. The probe was investigated for its recognition abilities in aqueous-organic mixture against various cations and anions. It shows a highly selective colorimetric response to Fe(II) ion by changing the colour from colourless to brownish pink. Chemo-sensitivity of the probe was investigated by absorption spectrometric titration with the Fe(II) ions. 1H NMR titration studies indicated imine nitrogen and one of the nitrogen in triazole ring was involved in complex formation with Fe2+ ion. Energy optimization studies by DFT method exhibits a marginal energy gap between ligand and Fe(II) complex (0.1166 eV) confirms the formation of metal ligand complex.

Keywords

Colorimetric chemo sensor Chromogenic Fe2 sensor 1,2,3-Triazole Absorption spectroscopy Energy minimization
Senthilkumaran, G., & Senthil, S. (2020). Synthesis and Characterization of 1,2,3-Triazole Containing Fe(II) Sensor. Asian Journal of Chemistry, 32(5), 1033–1038. Retrieved from https://asianpubs.org/index.php/ajchem/article/view/2458
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References
  1. S. Fakih, M. Podinovskaia, X. Kong, H.L. Collins, U.E. Schaible and R.C. Hider, J. Med. Chem., 51, 4539 (2008); https://doi.org/10.1021/jm8001247
  2. S.J. Lippard and J.M. Berg, Principles of Bioinorganic Chemistry, University Science Books, Mill Valley, 1994.
  3. W. Kaim and B. Schwederski, Bioinorganic Chemistry, 2nd ed., Wiley, New York, 1995.
  4. E.L. Que, D.W. Domaille and C.J. Chang, Chem. Rev., 108, 1517 (2008); https://doi.org/10.1021/cr078203u
  5. D.W. Domaille, E.L. Que and C.J. Chang, Nat. Chem. Biol., 4, 168 (2008); https://doi.org/10.1038/nchembio.69
  6. K.L. Haas and K.J. Franz, Chem. Rev., 109, 4921 (2009); https://doi.org/10.1021/cr900134a
  7. R. Mc rae, P. Bagchi, S. Sumalekshmy and C. Fahrni, Chem. Rev., 109, 4780 (2009).
  8. L. Zecca, M.B.H. Youdim, P. Riederer, J.R. Connor and R.R. Crichton, Nat. Rev. Neurosci., 5, 863 (2004); https://doi.org/10.1038/nrn1537
  9. M. Chen, H. Xiong, W. Wen, X. Zhang, H. Gu and S. Wang, Electrochim. Acta, 114, 265 (2013); https://doi.org/10.1016/j.electacta.2013.10.122
  10. J.E.T. Andersen, Analyst (Lond.), 130, 385 (2005); https://doi.org/10.1039/b412061b
  11. J. Nandre, S. Patil, P. Patil, S. Sahoo, C. Redshaw, P. Mahulikar and U. Patil, J. Fluoresc., 24, 1563 (2014); https://doi.org/10.1007/s10895-014-1438-4
  12. A.J. Weerasinghe, C. Schmiesing, S. Varaganti, G. Ramakrishna and E. Sinn, J. Phys. Chem. B, 114, 9413 (2010); https://doi.org/10.1021/jp1034568
  13. C.M. Carr, Chemistry of the Textile Industry, Blackie Academic & Professional, London, 1995.
  14. C.A.J. Appelo, Dieke Postma, Geochemistry, Groundwater and Pollution, CRC Press, London, 2nd Edition, 2008.
  15. B. Kaur, N. Kaur and S. Kumar, Coord. Chem. Rev., 358, 13 (2018); https://doi.org/10.1016/j.ccr.2017.12.002
  16. S. Santhoshkumar, K. Velmurugan, J. Prabhu, G. Radhakrishnan and R. Nandhakumar, Inorg. Chim. Acta, 439, 1 (2016); https://doi.org/10.1016/j.ica.2015.09.030
  17. Chem. Sci. J., 8, 1 (2017); https://doi.org/10.1039/C7SC90001E
  18. H. Kim, Y. Seo, Y. Youn, H. Lee, M. Yang and C. Kim, ChemistrySelect, 4, 1199 (2019); https://doi.org/10.1002/slct.201803415
  19. Y. Hong, S. Chen, C.W.T. Leung, J.W.Y. Lam, J. Liu, N.-W. Tseng, R.T.K. Kwok, Y. Yu, Z. Wang and B.Z. Tang, ACS Appl. Mater. Interfaces, 3, 3411 (2011); https://doi.org/10.1021/am2009162
  20. P. Li, L. Fang, H. Zhou, W. Zhang, X. Wang, N. Li, H. Zhong and B. Tang, Chemistry, 17, 10520 (2011); https://doi.org/10.1002/chem.201101327
  21. Y.S. Kim, G.J. Park, J.J. Lee, S.Y. Lee, S.Y. Lee and C. Kim, RSC Advances, 5, 11229 (2015); https://doi.org/10.1039/C4RA13291B
  22. Y.W. Choi, G.J. Park, Y.J. Na, H.Y. Jo, S.A. Lee, G.R. You and C. Kim, Sens. Actuators B Chem., 194, 343 (2014); https://doi.org/10.1016/j.snb.2013.12.114
  23. P.S. Hariharan and S.P. Anthony, Spectrochim. Acta A Mol. Biomol. Spectrosc., 136, 1658 (2015); https://doi.org/10.1016/j.saa.2014.10.061
  24. S. Wang, S.-Y. Gwon and S.-H. Kim, Spectrochim. Acta A Mol. Biomol. Spectrosc., 76, 293 (2010); https://doi.org/10.1016/j.saa.2009.12.018
  25. Y.W. Choi, G.J. Park, Y.J. Na, H.Y. Jo, S.A. Lee, G.R. You and C. Kim, Sensors and Sctuators B Chemical, 194, 343 (2014); https://doi.org/10.1016/j.snb.2013.12.114
  26. P.G. Mahajan, D.P. Bhopate, A.A. Kamble, D.K. Dalavi, G.B. Kolekar and S.R. Patil, Anal. Methods, 7, 7889 (2015); https://doi.org/10.1039/C5AY01461A
  27. F. Salimi, M. Kiani, C. Karami and M.A. Taher, Optik (Stuttg.), 158, 813 (2018); https://doi.org/10.1016/j.ijleo.2018.01.006
  28. H.C. Kolb and K.B. Sharpless, Drug Discov. Today, 8, 1128 (2003); https://doi.org/10.1016/S1359-6446(03)02933-7
  29. T.L. Mindt, C. Schweinsberg, L. Brans, A. Hagenbach, U. Abram, D. Tourwé, E. Garcia-Garayoa and R. Schibli, ChemMedChem, 4, 529 (2009); https://doi.org/10.1002/cmdc.200800418
  30. B. Rathinam, C.-C. Chien, B.-C. Chen and J.-H. Liu, Tetrahedron, 69, 235 (2013); https://doi.org/10.1016/j.tet.2012.10.040
  31. T.-J. Jia, W. Cao, X.-J. Zheng and L.-P. Jin, Tetrahedron Lett., 54, 3471 (2013); https://doi.org/10.1016/j.tetlet.2013.04.115
  32. A.N. Gusev, V.F. Shul’gin, S.B. Meshkova, S.S. Smola and W. Linert, J. Lumin., 155, 311 (2014); https://doi.org/10.1016/j.jlumin.2014.06.054
  33. S. Malkondu and S. Erdemir, Tetrahedron, 70, 5494 (2014); https://doi.org/10.1016/j.tet.2014.06.115
  34. M. Saleem, S.K. Kang and K.H. Lee, J. Lumin., 162, 14 (2015); https://doi.org/10.1016/j.jlumin.2015.02.004
  35. K.-C. Chang, I.-H. Su, G.-H. Lee and W.-S. Chung, Tetrahedron Lett., 48, 7274 (2007); https://doi.org/10.1016/j.tetlet.2007.08.045
  36. K.-C. Chang, I.-H. Su, A. Senthilvelan and W.-S. Chung, Org. Lett., 9, 3363 (2007); https://doi.org/10.1021/ol071337+
  37. Y.-J. Zhang, X.-P. He, M. Hu, Z. Li, X.-X. Shi and G.-R. Chen, Dyes Pigments, 88, 391 (2011); https://doi.org/10.1016/j.dyepig.2010.08.010
  38. M. Song, Z. Sun, C. Han, D. Tian, H. Li and J.S. Kim, Chem. Asian J., 9, 2344 (2014); https://doi.org/10.1002/asia.201400024
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