Synthesis and Characterization of the Metal Complexes of Thiourea Derived from 3-Amino-5-Methylisoxazole.

Abstract

The complexes of Fe(III),  Co(II), Ni(II), Cu(II) and Zn(II) with ligands derived from 3-amino-5-methylisoxazole and benzoyl thiocyanate have been synthesized and their structural characterization carried cut by elemental analysis, conductance, thermal, magnetic and infrared, electronic and ESR spectral data. Relevant conclusions with respect to the ligating behaviour of the ligands and the geometry of the metal complexes together with the nature of metal-ligand bonding present in them have been drawn based on the data obtained.