Reactivity of Tri-3-Phenyl Propyl Phosphate in the Form of its Conjugate Acid Species
Corresponding Author(s) : R. Patil
Asian Journal of Chemistry,
Vol. 7 No. 4 (1995): Vol 7 Issue 4
Abstract
Kinetics of hydrolysis of tri-3-phenyl propyl phosphate has been investigated from 0.1 to 7.0 mol dm–3 in HCl at 98ºC in 20% dioxane-water mixture (v/v). Ionic strength data exhibit the participation of conjugate acid species. Unimolecular behaviour has been decided by molecularity data studies. Solvent isotope effect study favours specific acid catalysis. The formation of a transition state has been observed by solvent effect study. Carbon-oxygen bond fission has been further strengthened by comparative kinetic data.
Keywords
Reactivity
Tri-3-Phenyl Propyl Phosphate
Conjugate Acid Species
Shinde, C., & Patil, R. (2010). Reactivity of Tri-3-Phenyl Propyl Phosphate in the Form of its Conjugate Acid Species. Asian Journal of Chemistry, 7(4), 877–880. Retrieved from https://asianpubs.org/index.php/ajchem/article/view/24450
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