Kinetics of Chloramine-T Oxidation of p-Hydroxy Benzoic Acid in Perchloric Acid: A Mechanistic Study
Corresponding Author(s) : U.S. Pandey
Asian Journal of Chemistry,
Vol. 7 No. 3 (1995): Vol 7 Issue 3
Abstract
Kinetic results in chloramine-T oxidation of p-hydroxy benzoic acid in perchloric acid have been reported. First order kinetics with respect to each of chloramine-T, p-hydroxy benzoic acid (p-HBA) and H+ ions has been observed. Zero effect of variation of ionic strength of the medium on the rate of the reaction has been obtained,. Successive addition of p-toluene suphonamide (PTS) did not influence the reaction rate. A suitable mechanism in conformity with observed kinetic results has been proposed.
Keywords
Kinetics
Chloramine-T Oxidation
p-Hydroxy Benzoic Acid
Perchloric Acid
Mechanistic Study
Pandey, U., & Kishore Roy, N. (2010). Kinetics of Chloramine-T Oxidation of p-Hydroxy Benzoic Acid in Perchloric Acid: A Mechanistic Study . Asian Journal of Chemistry, 7(3), 681–684. Retrieved from https://asianpubs.org/index.php/ajchem/article/view/24386
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