Kinetics of Oxidation of L-Malic Acid by Mn(III) Pyrophosphate
Corresponding Author(s) : R.P. Gupta
Asian Journal of Chemistry,
Vol. 8 No. 4 (1996): Vol 8 Issue 4
Abstract
The oxidation of L-malic acid by Mn(III) pyrophosphate in sulphuric
acid medium has been found to be first order with respect to Mn(III). The
oxidation rate has been found to increase with [malic acid], [H+] decreases
inversely with [pyrophosphate] free. Thermodynamic parameters have
been evaluated and a suitable mechanism involving complex formation
and free radicals is proposed.
Keywords
Kinetics
Oxidation
L-Malic Acid
Mn(III)
Pyrophosphate
(1)
Tripathi, R.; Gupta, R. Kinetics of Oxidation of L-Malic Acid by Mn(III) Pyrophosphate . ajc 2010, 8, 665-668.
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