Photochemical Oxidation of 2-Imidazolidinethione by Uranyl Acetate
Corresponding Author(s) : V.K. Vaidya
Asian Journal of Chemistry,
Vol. 8 No. 3 (1996): Vol 8 Issue 3
Abstract
Photochemical oxidation of 2-imidazolidinethione by uranyl acetate in
presence of perchloric acid has been studied at pH 2.0. 2-lmidazolidone,
sulphur, sulphur dioxide and sulphuric acid have been characterized as the
photoproducts. The presence of uranium(V) as an intermediate has been
proved spectrophotometrically. A probable mechanism has been proposed
involving excited state charge transfer complex (exciplex) formation.
Keywords
Photochemical Oxidation
2-Imidazolidinethione
Uranyl Acetate
(1)
Sharma, R.; Kabra, B.; Vaidya, V. Photochemical Oxidation of 2-Imidazolidinethione by Uranyl Acetate. ajc 2010, 8, 500-504.
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