Photochemical Oxidation of 2-Imidazolidinethione by Uranyl Acetate
Corresponding Author(s) : V.K. Vaidya
Asian Journal of Chemistry,
Vol. 8 No. 3 (1996): Vol 8 Issue 3
Abstract
Photochemical oxidation of 2-imidazolidinethione by uranyl acetate in
presence of perchloric acid has been studied at pH 2.0. 2-lmidazolidone,
sulphur, sulphur dioxide and sulphuric acid have been characterized as the
photoproducts. The presence of uranium(V) as an intermediate has been
proved spectrophotometrically. A probable mechanism has been proposed
involving excited state charge transfer complex (exciplex) formation.
Keywords
Photochemical Oxidation
2-Imidazolidinethione
Uranyl Acetate
Sharma, R., Kabra, B., & Vaidya, V. (2010). Photochemical Oxidation of 2-Imidazolidinethione by Uranyl Acetate. Asian Journal of Chemistry, 8(3), 500–504. Retrieved from https://asianpubs.org/index.php/ajchem/article/view/24097
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