A Systematic Kinetic Study of Oxidation of p-Toluidine by Chromic Acid
Corresponding Author(s) : Ranveer Singh
Asian Journal of Chemistry,
Vol. 8 No. 2 (1996): Vol 8 Issue 2
Abstract
The oxidation kinetics of p-toluidine have been studied by chromic acid
in acetic acid-water medium. The orders in oxidant, substrate and H+ have
been obtained one in each. The primary salt effect on the rate of oxidation
is negligible. The effect of catalyst such as Ag+, Cu2+ shows increasing
effect whereas Mn2+ has retarded the rate. Various thermodynamic
parameters have been evaluated. A probable mechanism has been suggested
on the basis of kinetic results.
Keywords
Systematic
Kinetic Study
Oxidation
p-Toluidine
Chromic Acid
Singh, R., & Shrivastava, K. (2010). A Systematic Kinetic Study of Oxidation of p-Toluidine by Chromic Acid . Asian Journal of Chemistry, 8(2), 293–297. Retrieved from https://asianpubs.org/index.php/ajchem/article/view/24066
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