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Vol. 31 No. 5 (2019): Vol 31 Issue 5

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Unusual Cleavage of N-N Bond of 1-Arylamino-1,2,3-triazole Derivatives: A Simple and Alternate Approach to 4,5-Disubstituted-1H-1,2,3-triazoles

https://doi.org/10.14233/ajchem.2019.21857
R. Nagarajan
Department of Chemistry, Karunya University, Karunya Nagar, Coimbatore-641114, India
L. Emmanuvel
Department of Chemistry, Karunya University, Karunya Nagar, Coimbatore-641114, India

Corresponding Author(s) : L. Emmanuvel

emmanuvel@karunya.edu

Asian Journal of Chemistry, Vol. 31 No. 5 (2019): Vol 31 Issue 5

Abstract

In this communication, the authors described the synthesis of 1-arylamino-1,2,3-triazole derivatives via diazo transfer reaction on active methylene hydrazones. Further, we have observed the reduction of 1-arylamino-1,2,3-triazole using Pd/C, H2 to result in unusual N-N bond cleavage to give 4,5-disubstituted-1H-1,2,3-triazole.

Keywords

N-N bond cleavage Reduction 1,2,3-Triazole 1-Amino-1,2,3-triazole Diazo transfer reaction
Nagarajan, R., & Emmanuvel, L. (2019). Unusual Cleavage of N-N Bond of 1-Arylamino-1,2,3-triazole Derivatives: A Simple and Alternate Approach to 4,5-Disubstituted-1H-1,2,3-triazoles. Asian Journal of Chemistry, 31(5), 1057–1061. https://doi.org/10.14233/ajchem.2019.21857
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