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Vol. 9 No. 4 (1997): Vol 9 Issue 4

Mechanism of Ru (III) Catalysed Oxidation of o-Hydroxybenzoic Acid by Acidic Solution of Bromamine-B

B K.K. Singh
Post-Graduate Department of Chemistry Maharaja College, Arrah-802 301 India
Nirmala Singh
Post-Graduate Department of Chemistry Maharaja College, Arrah-802 301 India
Narendra Kumar
Post-Graduate Department of Chemistry Maharaja College, Arrah-802 301 India
Ashok K. Singh
Post-Graduate Department of Chemistry Maharaja College, Arrah-802 301 India
B.K. Singh
Post-Graduate Department of Chemistry Maharaja College, Arrah-802 301 India

Corresponding Author(s) : B.K. Singh

Asian Journal of Chemistry, Vol. 9 No. 4 (1997): Vol 9 Issue 4

Abstract

The kinetics of Ru(III) catalysed oxidation of o-hydroxy benzoic acid (o-HBA) by acidic solution of bromamine-B has been studied. The results indicate that order of the reaction with respect to each of bromamine-B, o-HBA, Ru(III) and H+ ion is one. Negligible
effect of addition of potassium chloride and benzene sulphonamide
was observed. A suitable mechanism in conformity with kinetic data
has been proposed.

Keywords

Ru(III) Catalysed Oxidation o-Hydroxybenzoic Acid Acidic Solution Bromamine-B
(1)
K.K. Singh, B.; Singh, N.; Kumar, N.; K. Singh, A.; Singh, B. Mechanism of Ru (III) Catalysed Oxidation of O-Hydroxybenzoic Acid by Acidic Solution of Bromamine-B. ajc 2010, 9, 863-865.
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