A Study of Reactions of WCl6, WOCl4 and WO2Cl2 with Alcohols— Synthesis of Dialkoxy Derivatives of Tungsten
Corresponding Author(s) : M.K. Rastogi
Asian Journal of Chemistry,
Vol. 9 No. 3 (1997): Vol 9 Issue 3
Abstract
Dialkoxy derivatives of the type (RO)2WOCl2, (RO)2WO2 and
(RO)2WCl3 have been prepared and characterized. The starting
materials are tungsten(VI) oxychlorides WOCl4, WO2Cl2 and
tungsten hexachloride WCl6. It has been observed that WCl6
undergoes reduction to yield tungsten(V) dialkoxy derivatives.
These alkoxides have been characterized by elemental analysis, IR
and electronic spectra; while magnetic and conductivity measurements
have been carried out in some cases.
Keywords
WCl6
WOCl4
WO2Cl2
Alcohols
Synthesis
Dialkoxy Derivatives
Tungsten
Dabas, P., Saxena, R., & Rastogi, M. (2010). A Study of Reactions of WCl6, WOCl4 and WO2Cl2 with Alcohols— Synthesis of Dialkoxy Derivatives of Tungsten . Asian Journal of Chemistry, 9(3), 457–461. Retrieved from https://asianpubs.org/index.php/ajchem/article/view/23900
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