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Effect of Magnetic Treatment on Temporary Hardness of Groundwater
Corresponding Author(s) : Abdulaziz Ali Alomari
Asian Journal of Chemistry,
Vol. 31 No. 5 (2019): Vol 31 Issue 5
Abstract
The magnetic treatment devices for water have been in use for scale prevention several decades ago. Although, the effect of magnetic treatment on the chemical and physical properties of water is not fully understood and needs to make a lot of research effort to be clarified. This work aims to investigate the effect of the magnetic treatment on the temporary hardness of the groundwater. A sample of groundwater was passed twice under the influence of perpendicular magnetic strength 0.5 Tesla with a flow rate of 10 L/h. The temporary and permanent hardness as well as scale formation test were measured before and after the magnetic treatment. The scale was analyzed by XRD and SEM techniques. The temporary hardness and the weight of scales were reduced after the magnetic treatment by 39.1 and 22.3 %, respectively. The decrease of temporary hardness after the magnetic treatment of groundwater may be attributed to that the magnetic field reduces both the dissolved CO2 content and surface tension, both of which reduce the amount of temporary hardness. The SEM micrographs illustrate that the magnetic treatment modified the shape and size of crystals of CaCO3 scales to prevent its adhesion to the substrate forming hard scales. The XRD patterns prove that the magnetic treatment of groundwater enhances the crystallization of amorphous CaCO3 favouring the formation of calcite.
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References
J. Glater, J.L. York and K.S. Campbell, eds.: K.S. Spiegler and A.D.K. Laird, In: Principles of Desalination, Part B, Academic Press: New York, edn 2, Chap. 10 (1980).
X.F. Pang and Y.P. Feng, Chem. Phys. Lett., 373, 392 (2003); https://doi.org/10.1016/S0009-2614(03)00576-1.
I. Otsuka and S. Ozeki, J. Phys. Chem. B, 110, 1509 (2006); https://doi.org/10.1021/jp056198x.
K. Higashitani, H. Iseri, K. Okuhara, A. Kage and S. Hatade, J. Coll. Int. Sci., 172, 383 (1995); https://doi.org/10.1006/jcis.1995.1268.
I.H. Ibrahim, Egypt. J. Sol., 29, 363 (2006).
S. Kobe, G. Drazic, P.J. McGuiness, T. Meden, E. Sarantopoulou, Z. Kollia and A.C. Cefalas, Mater. Sci. Eng. C, 23, 811 (2003); https://doi.org/10.1016/j.msec.2003.09.136.
J.S. Baker and S.J. Judd, Water Res., 30, 247 (1996); https://doi.org/10.1016/0043-1354(95)00184-0.
C. Gabrielli, R. Jaouhari, G. Maurin and M. Keddam, Water Res., 35, 3249 (2001); https://doi.org/10.1016/S0043-1354(01)00010-0.
E. Chibowski, A. Szcze’s and L. Holysz, Langmuir, 21, 8114 (2005); https://doi.org/10.1021/la050575f.
A. Fathi, T. Mohamed, G. Claude, G. Maurin and B.A. Mohamed, Water Res., 40, 1941 (2006); https://doi.org/10.1016/j.watres.2006.03.013.
M.A. Tantawy, A.A. Alomari, H.M.A. Alghamdi, R.S.A. Alzahrani and S.M.A. Alsehami, Int. J. Eng. Res. Technol., 4, 824 (2015).
N. Saksono, M. Gozan, S. Bismo, E. Krisanti, R. Widaningrum and S.K. Song, Korean J. Chem. Eng., 25, 1145 (2008); https://doi.org/10.1007/s11814-008-0188-x.
M.G. Farhan, J.D. Mahal and A.B. Mohammed, Tikrit J. Pure Sci., 22, 23 (2017).
A.S. Hasaani, Z.L. Hadi and K.A. Rasheed, Int. J. Basic Appl. Sci., 3, 1 (2015).
J.M.D. Coey and S. Cass, J. Magn. Magn. Mater., 209, 71 (2000); https://doi.org/10.1016/S0304-8853(99)00648-4.
Z.Z.K. Khater and M.H. Ibraheim, Int. J. Curr. Res. Acad. Rev., 308, 262 (2015).
A. Kotb, Energy Power Eng., 5, 422 (2013); https://doi.org/10.4236/epe.2013.56045.
R.S.A. Hady, M.A.A.Younes, A.M. Ibrahim and M.M.A. Aziz, J. Adv. Res., 2, 351 (2011); https://doi.org/10.1016/j.jare.2011.01.009.
E.A. Duffy, Ph.D. Thesis, Investigation of Magnetic Water Treatment Devices, Clemson University, South Carolina: USA (1977).
C.E. Gruber and D.D. Carda, Measurable Parameters in Water Conditioning Equipment as Determined in Laboratory Simulations at Rapid City, South Dakota. Final Report Issued to the Water Quality Association, South Dakota School of Mines and Technology (1981).
J.E. Alleman, A Performance Evaluation for Magnetic Water Treatment, Fourth Domestic Water Quality Symposium, ASAE and Water Quality Association (1985).
M. Orb, Reducing Formation of Scale with Magnetic, Republic of Estonia Jogeva Co-educational Gymnasium (2007).
R.A. Stairs, Can. J. Chern., 73, 781 (1995); https://doi.org/10.1139/v95-098.
V.B. Fainerman, S.V. Lylyk, E.V. Aksenenko, N.M. Kovalchuk, V.I. Kovalchuk, J.T. Petkov and R. Miller, J. Colloid Interface Sci., 377, 1 (2012); https://doi.org/10.1016/j.jcis.2012.03.030.
H. Ben Amor, A. Elaoud, N. Ben Salah and K. Elmoueddeb, Int. J. Adv. Ind. Eng., 5, 119 (2017).
F. Lippmann, Sedimentary Carbonate Minerals, Springer: New York (1973).
R.A. Barrett and S.A. Parsons, Water Res., 32, 609 (1998); https://doi.org/10.1016/S0043-1354(97)00277-7.
K.J. Kronenberg, IEEE Trans. Magn., 21, 2059 (1985); https://doi.org/10.1109/TMAG.1985.1064019.
M.M. Tlili, M. Ben Amor, C. Gabrielli, S. Joiret and G. Maurin, Calcium Carbonate Precursors During Scaling Process, Communication First IWA Conference on Scaling and Corrosion in Water and Wastewater Systems, Cranfield University UK Full Text in Special Volume (2003).
P.W. Krauter, J.E. Harrar, S.P. Orloff and S.M. Bahowick, Test of a Magnetic Device for Amelioration of Scale Formation at Treatment Facility D. Internal Report, Lawrence Livermore National Laboratory, Osti 567404 (1996).