Adducts of WOCl4 and WO2Cl2 with Some Bases
Corresponding Author(s) : M.K. Rastogi
Asian Journal of Chemistry,
Vol. 9 No. 3 (1997): Vol 9 Issue 3
Abstract
Solutions of WOCl4 in benzene react with some Lewis bases to form 1:1 or 1:2 adducts with the Lewis bases (pyridine, o-phenanthroline, 2.2´-bipyridyl, aniline, o-, m-, p-toluidines, thiourea and anthracene), while WO2Cl2 react with some Lewis bases (pyridine,
2,2´-bipyridyl, formam ide, benzamide, urea, naphthalene,
anthracene and phenanthrene) in solvents like MeCN, DMSO etc.
to give 1 : 1 or 1 : 2 adducts. It appears that the Lewis base molecules
enter into the coordination sphere of tungsten.
Keywords
Adducts
WOCl4
WO2Cl2
Bases
(1)
Dabas, P.; Rastogi, M. Adducts of WOCl4 and WO2Cl2 With Some Bases . ajc 2010, 9, 445-452.
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