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Vol. 32 No. 7 (2020): Vol 32 Issue 7

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Synthesis, Characterization and DNA Binding Studies of N,N′-bis(2-Hydroxy-5-methylbenzylidene)- 2-hydroxy-propane-1,3-diamine Copper(II) and Nickel(II) Complexes

Ramina
Department of Chemistry, Manipur University, Canchipur-795003, India
https://orcid.org/0000-0002-2748-5111
Rajkumar Bhubon Singh
Department of Chemistry, Manipur University, Canchipur-795003, India
Oinam U-wang
Department of Chemistry, Manipur University, Canchipur-795003, India
https://orcid.org/0000-0001-7407-7674
Thoudam Surchandra Singh
Department of Chemistry, Manipur University, Canchipur-795003, India
https://orcid.org/0000-0001-9603-7139
T. Tiakaba Jamir
Department of Chemistry, Kohima Science College, Kohima-797002, India
https://orcid.org/0000-0001-7087-0907

Corresponding Author(s) : Rajkumar Bhubon Singh

bhubonsingh@gmail.com

Asian Journal of Chemistry, Vol. 32 No. 7 (2020): Vol 32 Issue 7

Abstract

Two new Schiff base transition metal complexes [Cu(HL)]2.CH3CH2OH (1) and [Ni(HL)] (2) (L = N,N′-bis(2-hydroxy-5-methyl-benzylidene)-2-hydroxy-propane-1,3-diamine) were synthesized and characterized by different physico-chemical and spectroscopic techniques. Structure of complex 1 was determined by single crystal X-ray diffractometer. Both the complexes have distorted square planar geometry. The DNA binding study of two complexes was performed via electronic absorption, cyclic voltammetry, photoluminescence, and viscosity methods and found to be intercalative mode of binding.

Keywords

Schiff base Cu(II) and Ni(II) complexes DNA binding
Ramina, ., Singh, R. B., U-wang, O., Singh, T. S., & Jamir, T. T. (2020). Synthesis, Characterization and DNA Binding Studies of N,N′-bis(2-Hydroxy-5-methylbenzylidene)- 2-hydroxy-propane-1,3-diamine Copper(II) and Nickel(II) Complexes. Asian Journal of Chemistry, 32(7), 1667–1675. Retrieved from https://asianpubs.org/index.php/ajchem/article/view/2388
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