Kinetics and Mechanism of Oxidation of Formaldehyde with Bi(V) in HClO4-HF Mixture

C.S. Jha; Vijay Kumar Jha; Sushil Jha; Prem Mohan Mishra

Issue

Vol. 10 No. 4 (1998): Vol 10 Issue 4

Issue Published : 30 October 1998

Kinetics and Mechanism of Oxidation of Formaldehyde with Bi(V) in HClO4-HF Mixture

C.S. Jha

Department of Chemistry, Lalit Narayan Mithila University, Darbhanga, India

Vijay Kumar Jha

Department of Chemistry, Lalit Narayan Mithila University, Darbhanga, India

Sushil Jha

Department of Chemistry, Lalit Narayan Mithila University, Darbhanga, India

Prem Mohan Mishra

Department of Chemistry, Lalit Narayan Mithila University, Darbhanga, India

Corresponding Author(s) : C.S. Jha

Asian Journal of Chemistry, Vol. 10 No. 4 (1998): Vol 10 Issue 4
Article Published : 30 March 2010

Abstract

Kinetics of oxidation of formaldehyde with Bi(V) fluoride complex have been investigated in HCIO₄-HF mixture. The reaction is first order in each reactant. Hydrogen ion and ionic strength (HP) and added fluoride (F^- ) have no effect on the reaction rates. The mode of electron transference for the substrate (HCOOH) to the oxidant [Bi(V)] has been indicated via. a bridged outer sphere mechanism.

Keywords

Kinetics Mechanism Oxidation Formaldehyde Bi(V) HClO4-HF Mixture

(1)

Jha, C.; Kumar Jha, V.; Jha, S.; Mohan Mishra, P. Kinetics and Mechanism of Oxidation of Formaldehyde With Bi(V) in HClO4-HF Mixture . ajc 2010, 10, 861-865.

Issue

Vol. 10 No. 4 (1998): Vol 10 Issue 4

Kinetics and Mechanism of Oxidation of Formaldehyde with Bi(V) in HClO4-HF Mixture

Corresponding Author(s) : C.S. Jha

Abstract

Keywords

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