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Vol. 32 No. 7 (2020): Vol 32 Issue 7

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Substrate Inhibition in Ruthenium(III) Catalyzed Oxidation of Propane-1,3-diol by Periodate in Acidic Medium: A Kinetic Study

K.V.S. Koteswara Rao
Department of Chemistry, G.V.S.M. Government Degree College, Ulavapadu-523292, India
https://orcid.org/0000-0003-4370-0878
R. Venkata Nadh
Department of Chemistry, GITAM University-Bengaluru Campus, Bengaluru-562163, India
https://orcid.org/0000-0003-0925-1132
K. Venkata Ratnam
Department of Chemistry, GITAM University-Bengaluru Campus, Bengaluru-562163, India
https://orcid.org/0000-0002-2872-9333

Corresponding Author(s) : R. Venkata Nadh

doctornadh@yahoo.co.in

Asian Journal of Chemistry, Vol. 32 No. 7 (2020): Vol 32 Issue 7

Abstract

Ruthenium(III) catalyzed oxidation of propane-1,3-diol by potassium periodate was studied in aqueous perchloric acid medium. Orders of reaction with respect to concentrations of oxidant, substrate, acid and catalyst were determined. First order in oxidant and catalyst concentrations, and inverse fractional order in acid medium were observed. In addition, substrate inhibition (i.e. a decrease in reaction rate with an increase in substrate concentration) was observed. Effect of addition of salt and solvent was studied. Based on the studies of temperature variation, Arrhenius parameters were calculated. Plausible mechanism was also proposed based on observed kinetics.

Keywords

Ruthenium(III) Propane-1,3-diol Oxidation Acidic medium Potassium periodate Kinetics
Koteswara Rao, K., Nadh, R. V., & Ratnam, K. V. (2020). Substrate Inhibition in Ruthenium(III) Catalyzed Oxidation of Propane-1,3-diol by Periodate in Acidic Medium: A Kinetic Study. Asian Journal of Chemistry, 32(7), 1569–1575. Retrieved from https://asianpubs.org/index.php/ajchem/article/view/2371
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