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Vol. 32 No. 7 (2020): Vol 32 Issue 7

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Effect of Modified Eggshell on Adsorption Capacity of Chromium(VI) from Aqueous Solution

Abdulaziz Ali Alomari
Department of Chemistry, Faculty of Science and Arts, Mukwah, Albaha University, Albaha, Saudi Arabia
https://orcid.org/0000-0002-7678-082X

Corresponding Author(s) : Abdulaziz Ali Alomari

abomaz1389@yahoo.com

Asian Journal of Chemistry, Vol. 32 No. 7 (2020): Vol 32 Issue 7

Abstract

The aim of this work is to investigate the use of eggshell for adsorption of Cr(VI) from aqueous solution and the effect of thermal treatment as well as coating with Fe2O3 of eggshell on the extraction percent of Cr(VI). The XRD, FTIR and SEM techniques proved that the eggshell mainly composed of calcite rhombohedral structure in addition to a trace of quartz silica residual protein fibers. Heating at 550 ºC does not decompose eggshell but decomposes the residual protein. The effect of pH, weight of eggshell adsorbent, contact time, and initial concentration of Cr(VI) ions on the adsorption of Cr(VI) on eggshell sorbents were determined under static conditions by the batch equilibrium technique. The sorption kinetic as well as mechanistic isotherm parameters of Cr(VI) on the eggshell sorbent, were analyzed. It was concluded that the adsorption of Cr(VI) on eggshell increases as pH increases in the range 3-7, then, with decreases at higher pH. The extraction percent of Cr(VI) increases with an increase in the dosage of eggshell sorbents. The optimum dosage of eggshell adsorbents was found to be 5 g after which the extraction percent of Cr(VI) did not marked increase. The extraction percent of Cr(VI) by eggshell sorbents rapidly increases within 60 min followed by a slower extraction after that when maximum adsorption was reported. The adsorption capacity of Cr(VI) ions is slightly reduced in case of heated eggshell due to the change that occurs in the pore size distribution and structure of eggshell during heating. Hence, the thermal treatment and coating with Fe2O3 do not affect the chemical structure of eggshell sorbents. The adsorption kinetics data were best fitted with the pseudo-second-order equation and the adsorption isotherms were best fitted with the Langmuir isotherm model.

Keywords

Eggshell sorbents Adsorption Chromium(VI) Pseudo-second-order sorption Langmuir isotherm
Alomari, A. A. (2020). Effect of Modified Eggshell on Adsorption Capacity of Chromium(VI) from Aqueous Solution. Asian Journal of Chemistry, 32(7), 1549–1556. Retrieved from https://asianpubs.org/index.php/ajchem/article/view/2369
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References
  1. I.Y. El-Sherif, S. Tolani, K. Ofosu, O.A. Mohamed and A.K. Wanekaya, J. Environ. Manage., 129, 410 (2013); https://doi.org/10.1016/j.jenvman.2013.08.004
  2. H. Javadian, J. Ind. Eng. Chem., 20, 4344 (2014); https://doi.org/10.1016/j.jiec.2014.01.042
  3. N. Meunier, P. Drogui, C. Montane, R. Hausler, G. Mercier and J.F. Blais, J. Hazard. Mater., 137, 581 (2006); https://doi.org/10.1016/j.jhazmat.2006.02.050
  4. S.K. Sahu, P. Meshram, B.D. Pandey, V. Kumar and T.R. Mankhand, Hydrometallurgy, 99, 170 (2009); https://doi.org/10.1016/j.hydromet.2009.08.002
  5. P. Religa, A. Kowalik and P. Gierycz, Sep. Purif. Technol., 82, 114 (2011); https://doi.org/10.1016/j.seppur.2011.08.032
  6. A.K. Golder, A.N. Samanta and S. Ray, Sep. Purif. Technol., 53, 33 (2007); https://doi.org/10.1016/j.seppur.2006.06.010
  7. S. Tiglyene, A. Jaouad and L. Mandi, Environ. Technol., 29, 613 (2008); https://doi.org/10.1080/09593330801983888
  8. L. Mandi, S. Tiglyene and A. Jaouad, eds.: M. El Moujabber, L. Mandi, G. Trisorio-Liuzzi, I. Martín, A. Rabi and R. Rodríguez, Depuration of Tannery Effluent by Phytoremediation and Infiltration Percolation Under Arid Climate, In: Technological Perspectives for Rational Use of Water Resources in the Mediterranean Region, Bari CIHEAM, pp. 199-205 (2009).
  9. M. Bhaumik, K. Setshedi, A. Maity and M.S. Onyango, Sep. Purif. Technol., 110, 11 (2013); https://doi.org/10.1016/j.seppur.2013.02.037
  10. Y. Sun, Q. Yue, Y. Mao, B. Gao, Y. Gao and L. Huang, J. Hazard. Mater., 265, 191 (2014); https://doi.org/10.1016/j.jhazmat.2013.11.057
  11. N. Sankararamakrishnan, M. Jaiswal and N. Verma, Chem. Eng. J., 235, 1 (2014); https://doi.org/10.1016/j.cej.2013.08.070
  12. N.A. Fathy, S.T. El-Wakeel and R.R. Abd El-Latif, J. Environ. Chem. Eng., 3, 1137 (2015); https://doi.org/10.1016/j.jece.2015.04.011
  13. M. Naushad, Z.A. ALOthman, G. Sharma and Inamuddin, Ionics, 21, 1453 (2015); https://doi.org/10.1007/s11581-014-1292-z
  14. A.A. Alqadami, M. Naushad, M.A. Abdalla, T. Ahamad, Z. Abdullah Alothman and S.M. Alshehri, RSC Adv., 6, 22679 (2016); https://doi.org/10.1039/C5RA27525C
  15. A. Amalraj, M.K. Selvi, A. Rajeswari, E.J.S. Christy and A. Pius, J. Water Process Eng., 13, 88 (2016); https://doi.org/10.1016/j.jwpe.2016.08.013
  16. N. Ballav, A. Maity and S.B. Mishra, Chem. Eng. J., 198-199, 536 (2012); https://doi.org/10.1016/j.cej.2012.05.110
  17. A. Bhatnagar and M. Sillanpaa, Chem. Eng. J., 157, 277 (2010); https://doi.org/10.1016/j.cej.2010.01.007
  18. A.B. Albadarin, C. Mangwandi, A.H. Al-Muhtaseb, G.M. Walker, S.J. Allen and M.N.M. Ahmad, Chem. Eng. J., 179, 193 (2012); https://doi.org/10.1016/j.cej.2011.10.080
  19. A. Rajendran and C. Mansiya, Br. J. Environ. Climate Changes, 1, 44 (2011).
  20. W.Q. Tang, R.Y. Zeng, Y.L. Feng, X.M. Li and W. Zhen, Chem. Eng. J., 223, 340 (2013); https://doi.org/10.1016/j.cej.2013.02.094
  21. M.J. Quina, M.A.R. Soares and R. Quinta-Ferreira, Resour. Conserv. Recycling, 123, 176 (2017); https://doi.org/10.1016/j.resconrec.2016.09.027
  22. K. Kumaraswamy, B.V. Dhananjaneyulu, P. Vijetha and Y.P. Kumar, J. Pharm. Biol. Chem. Sci., 6, 529 (2015).
  23. H. Daraei, A. Mittal, M. Noorisepehr and J. Mittal, Desalination Water Treat., 53, 214 (2015); https://doi.org/10.1080/19443994.2013.837011
  24. H. Daraei, A. Mittal, J. Mittal and H. Kamali, Desalination Water Treat., 52, 1307 (2014); https://doi.org/10.1080/19443994.2013.787374
  25. T. Ravi and S. Sundararaman, J. Environ. Chem. Eng., 8, 103877 (2020); https://doi.org/10.1016/j.jece.2020.103877
  26. H.J. Park, S.W. Jeong, J.K. Yang, B.G. Kim and S.M. Lee, J. Environ. Sci. (China), 19, 1436 (2007); https://doi.org/10.1016/S1001-0742(07)60234-4
  27. D. Chen, X. Xiao and K. Yang, RSC Adv., 6, 35332 (2016); https://doi.org/10.1039/C6RA05034D
  28. C.J. Xin and N. Ngadi, PERINTIS eJournal, 8, 86 (2018).
  29. S. Elabbas, L. Mandi, F. Berrekhis, M.N. Pons, J.P. Leclerc and N. Ouazzani, J. Environ. Manage., 166, 589 (2016); https://doi.org/10.1016/j.jenvman.2015.11.012
  30. K. Chojnacka, J. Hazard. Mater., 121, 167 (2005); https://doi.org/10.1016/j.jhazmat.2005.02.004
  31. J.V. Flores-Cano, R. Leyva-Ramos, J. Mendoza-Barron, R.M. GuerreroCoronado, A. Aragón-Piña and G.J. Labrada-Delgado, J. Appl. Surf. Sci., 276, 682 (2013); https://doi.org/10.1016/j.apsusc.2013.03.153
  32. M. Ahmad, A.R.A. Usman, S.S. Lee, S.C. Kim, J.H. Joo, J.E. Yang and Y.S. Ok, J. Ind. Eng. Chem., 18, 198 (2012); https://doi.org/10.1016/j.jiec.2011.11.013
  33. W. Zheng, X.M. Li, Q. Yang, G.M. Zeng, X.X. Shen, Y. Zhang and J.J. Liu, J. Hazard. Mater., 147, 534 (2007); https://doi.org/10.1016/j.jhazmat.2007.01.048
  34. D. Liao, W. Zheng, X. Li, Q. Yang, X. Yue, L. Guo and G. Zeng, J. Hazard. Mater., 177, 126 (2010); https://doi.org/10.1016/j.jhazmat.2009.12.005
  35. S.M. Shaheen, F.I. Eissa, K.M. Ghanem, H.M.G. El-Din and F.S. Al Anany, J. Environ. Manage., 128, 514 (2013); https://doi.org/10.1016/j.jenvman.2013.05.061
  36. S.E. Ghazy and A.H.M. Gad, Indian J. Chem. Technol., 15, 433 (2008).
  37. S.E. Ghazy and A.H.M. Gad, Arab. J. Chem., 7, 277 (2014); https://doi.org/10.1016/j.arabjc.2010.10.031
  38. N. Yeddou and A. Bensmaili, Desalination, 206, 127 (2007); https://doi.org/10.1016/j.desal.2006.04.052
  39. M. Baláz, J. Ficeriová and J. Brianèin, Chemosphere, 146, 45 (2016); https://doi.org/10.1016/j.chemosphere.2015.12.002
  40. O. Eljamal, J. Okawauchi, K. Hiramatsu and M. Harada, Environ. Earth Sci., 68, 859 (2013); https://doi.org/10.1007/s12665-012-1789-6
  41. A.K. Patra, A. Dutta and A. Bhaumik, Chem. Eur. J., 19, 12388 (2013); https://doi.org/10.1002/chem.201301498
  42. T. Zaman, M. Mostari, M.A.A. Mahmood and M.S. Rahman, Ceramica, 64, 236 (2018); https://doi.org/10.1590/0366-69132018643702349
  43. F. Shen, M. Qiu, Y. Hua and X. Qi, ChemistrySelect, 3, 586 (2018); https://doi.org/10.1002/slct.201702496
  44. Z. Zhang, Y. Xie, X. Xu, H. Pan and R. Tang, J. Cryst. Growth, 343, 62 (2012); https://doi.org/10.1016/j.jcrysgro.2012.01.025
  45. Y. Wang, Y.X. Moo, C. Chen, P. Gunawan and R. Xu, J. Colloid Interface Sci., 352, 393 (2010); https://doi.org/10.1016/j.jcis.2010.08.060
  46. P.S. Guru and S. Dash, J. Dispers. Sci. Technol., 34, 1099 (2013); https://doi.org/10.1080/01932691.2012.737752
  47. J.A. Newman, P.D. Schmitt, S.J. Toth, F. Deng, S. Zhang and G.J. Simpson, Anal. Chem., 87, 10950 (2015); https://doi.org/10.1021/acs.analchem.5b02758
  48. S. Kaufhold, M. Hein, R. Dohrmann and K. Ufer, Vib. Spectrosc., 59, 29 (2012); https://doi.org/10.1016/j.vibspec.2011.12.012
  49. M. Fuji, J. Zhane, T. Takel, T. Watanabe, M. Chikazawa, T. Watanabe and K. Tanabe, Inorg. Mater., 4, 330 (1997).
  50. N. Ballav, H.J. Choi, S.B. Mishra and A. Maity, J. Ind. Eng. Chem., 20, 4085 (2014); https://doi.org/10.1016/j.jiec.2014.01.007
  51. P. Cubillas, S. Köhler, M. Prieto, C. Chaïrat and E. Oelkers, Chem. Geol., 216, 59 (2005); https://doi.org/10.1016/j.chemgeo.2004.11.009
  52. B. Liu and Y. Huang, J. Mater. Chem., 21, 17413 (2011); https://doi.org/10.1039/c1jm12329g
  53. J.M. Zachara, D.C. Girvin, R.L. Schmidt and C.T. Resch, Environ. Sci. Technol., 21, 589 (1987); https://doi.org/10.1021/es00160a010
  54. Z.T.A. Ali, M.A. Ibrahim and H.M. Madhloom, Al-Nahrain Univ. Coll. Eng. J., 19, 186 (2016).
  55. N. Ahalya, T.V. Ramachandra and R. Kanamadi, Res. J. Chem. Environ.,7, 71 (2003).
  56. H. Pahlavanzadeh, A.R. Keshtkar, J. Safdari and Z. Abadi, J. Hazard.Mater., 175, 304 (2010); https://doi.org/10.1016/j.jhazmat.2009.10.004
  57. W. Xiaofu, Z. Fang, C. Mingli, Z. Yangli, Z. Chong and Z. Hailan, J. Adsorp. Sci. Technol., 26, 145 (2008); https://doi.org/10.1260/026361708786036115
  58. E. Stefaniak, B. Bilinski, R. Dobrowolski, P. Staszczuk and J. Wojcik, Colloids Surf. A Physicochem. Eng. Asp., 208, 337 (2002); https://doi.org/10.1016/S0927-7757(02)00160-7
  59. H.S. Altundogan, Process Biochem., 40, 1443 (2005); https://doi.org/10.1016/j.procbio.2004.06.027
  60. X. Lv, Y. Hu, J. Tang, T. Sheng, G. Jiang and X. Xu, Chem. Eng. J., 218, 55 (2013); https://doi.org/10.1016/j.cej.2012.12.026
  61. M. El Haddad, R. Slimani, R. Mamouni, M.R. Laamari, S. Rafqah and S. Lazar, J. Taiwan Inst. Chem. Eng., 44, 13 (2013); https://doi.org/10.1016/j.jtice.2012.10.003
  62. Q. Qin, J. Ma and K. Liu, J. Hazard. Mater., 162, 133 (2009); https://doi.org/10.1016/j.jhazmat.2008.05.016
  63. N. Fiol, I. Villaescusa, M. Martínez, N. Miralles, J. Poch and J. Serarols, Separ. Purif. Tech., 50, 132 (2006); https://doi.org/10.1016/j.seppur.2005.11.016
  64. N.D. Hutson and R.T. Yang, Adsorption, 3, 189 (1997); https://doi.org/10.1007/BF01650130
  65. M. Erhayem, F. Al-Tohami, R. Mohamed and K. Ahmida, Am. J. Anal. Chem., 6, 1 (2015); https://doi.org/10.4236/ajac.2015.61001
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