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Vol. 32 No. 7 (2020): Vol 32 Issue 7

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Development and Characterization of SDS Doped Poly(aniline-co-2-isopropylaniline) MWCNT/CuO Nanocomposites for Electrochemical Supercapacitor Application

Kamal Kant Singh
Film Laboratory, Department of Materials Science & Nanotechnology, Deenbandhu Chhotu Ram University of Science & Technology, Murthal-131039, India
Ashok K. Sharma
Film Laboratory, Department of Materials Science & Nanotechnology, Deenbandhu Chhotu Ram University of Science & Technology, Murthal-131039, India

Corresponding Author(s) : Ashok K. Sharma

ashokksharma2k18@gmail.com

Asian Journal of Chemistry, Vol. 32 No. 7 (2020): Vol 32 Issue 7

Abstract

A novel electroactive nanocomposite material containing aniline-co-2-isopropylaniline (Pani-co), SDS doped poly-Pani-co, copper oxide (CuO), and multiwalled carbon nanotubes (MWCNTs) has been developed by in situ oxidative synthesis technique. The electrochemical execution of synthesised composite as electroactive supercapacitor material was examined through three electrode cell assembly viz. cyclic voltammetry (CV), galvanostatic charge/discharge analysis (GCD) and electrochemical impedance study. Physical and chemical characteristics of synthesized SDS doped Pani-co/MWCNT/CuO nanocomposite were explored via FTIR, TGA, XRD, FESEM and EDX methods. The results confirmed that the existence of metal oxide on MWCNTs enhanced the redox activity of the prepared composite. The maximum specific capacitance obtained in cyclic voltammetric studies was 1473 F/g at sweep rate of 3 mV/s, and the maximum specific capacitance obtained with GCD studies was 1512 F/g at current density of 1A/g in 1M Na2SO4 aqueous solution of with better cycle life.

Keywords

2-Isopropylaniline Carbon nanotubes Supercapacitor Voltammetry Charge-discharge Copper oxide
Singh, K. K., & Sharma, A. K. (2020). Development and Characterization of SDS Doped Poly(aniline-co-2-isopropylaniline) MWCNT/CuO Nanocomposites for Electrochemical Supercapacitor Application. Asian Journal of Chemistry, 32(7), 1779–1787. Retrieved from https://asianpubs.org/index.php/ajchem/article/view/2363
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