Synthesis of Novel 4,5-Dihydro-1,2,4,5-oxatriazine-6-one from the Reaction of Benzonitrile Oxide with 1-Ethoxycarbonyl-1-methylhydrazine
Corresponding Author(s) : Abed El-Rahman S. Ferwanah
Asian Journal of Chemistry,
Vol. 10 No. 1 (1998): Vol 10 Issue 1
Abstract
Benzonitrile oxide (2) reacts with 1-ethoxycarbonyl-1-methylhydrazine3 to give the acyclic hydrazidoxime (4) as a stable product,which cyclizes to the novel 4,5-dihydro-1,2,4,5-oxatriazine-6-one (5) uponstirring with NaH in dry THF at room temperature. The fragmentation of(5) in the mass spectrometer is discussed.
Keywords
Synthesis
Novel
4,5-Dihydro-1,2,4,5-oxatriazine-6-one
Benzonitrile Oxide
1-Ethoxycarbonyl-1-methylhydrazine
El-Rahman S. Ferwanah, A., & M. Awadallah, A. (2010). Synthesis of Novel 4,5-Dihydro-1,2,4,5-oxatriazine-6-one from the Reaction of Benzonitrile Oxide with 1-Ethoxycarbonyl-1-methylhydrazine. Asian Journal of Chemistry, 10(1), 180–184. Retrieved from https://asianpubs.org/index.php/ajchem/article/view/23569
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