A New Series of Ru(II) Polypyridine Surfactants: Synthesis, 2D NMR, Fluorescence, Electrochemistry and Electrochemiluminnescence
Corresponding Author(s) : Guoyi Zhu
Asian Journal of Chemistry,
Vol. 11 No. 4 (1999): Vol 11 Issue 4
Abstract
A new series of Ru(II) polypyridine surfactants, Ru(bpy)2[phenNHCO(CH2)nCH3](PF6)2, where n is10, 12, 14, or 16, has been prepared and characterized. The 1H-NMR spectra of these new Ru(II) complexes were attributed and discussed by the 1H-1H COSY method. The comparative
analysis of IR spectra of these complexes and their responding free ligands
has shown that there are intensive d→π* feedback interactions between
central Ru(II} and their ligands. Their fluorescent, electrochemical and
electrochemiluminescent behaviours are also reported.
Keywords
New Series
Ru(II)
Polypyridine Surfactants
Synthesis
2D NMR
Fluorescence
Electrochemistry
Electrochemiluminnescence
(1)
Wang, P.; Zhu, G. A New Series of Ru(II) Polypyridine Surfactants: Synthesis, 2D NMR, Fluorescence, Electrochemistry and Electrochemiluminnescence . ajc 2010, 11, 1307-1312.
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