Synthesis and Biological Activity of 2-Methylpiperazine-Dithiocarbamato and Di-(2-Methyl-5-Chloro phenyl) Dithiophosphinato Derivatives of Triorganation(IV) Chloride
Corresponding Author(s) : P.K. Gogoi
Asian Journal of Chemistry,
Vol. 11 No. 4 (1999): Vol 11 Issue 4
Abstract
Complexes of triphenyltin(IV) chloride with 2-methyl-piperazinedithiocarbamate (Na salt, 2-Mepipzdtc) and di-(2-methyl-5-chlorophenyl) diphosphinate (Na salt; MeCldtpi) have been synthesised and characterised by elemental analysis, IR and 1H-NMR studies. Unlike the symmetrical bidentate nature of the dithiocarbamato group an unsymmetrical
bidentate ligation is suggested for the dithiophosphinato group
towards organotin(IV) moiety. The thermal stability of the compounds,
biological activity against E. coli and potential antifungal role of the compounds
in wood preservation have been evaluated.
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