Mononuclear and Binuclear Complexes of Fe(II) and Cu(II) with 2,6-Diacetyl Pyridine and Phenlene Monoxime and Phenylene Diamine

Abstract

Mononuclear and binuclear complexes of types (ML¹-H²], [ML₁]X₂,

[ML₂]₂X₄, [ML₃]₂X₄, [M(L₂-H₂)]₂, [ML₃-H2]₂ where M = Fe(II) or

Cu(II), X = OAc^– or 0.5SO^2–₄, L₁ = bis-(2,6-diacetyl pyridine monoxime)

1,2-diamino benzene, L₂ = bis-(2,6-diacetylpyridine monoxime) 1,3-diamino

benzene, L₃ = bis-(2,6-diacetyl pyridine monoxime) 1,4-diaminobelizene

have been synthesised and characterised by elemental analysis, IR

electronic and magnetic susceptibility studies.