Issue

Vol. 31 No. 5 (2019): Vol 31 Issue 5

Copyright (c) 2019 AJC

Creative Commons License

This work is licensed under a Creative Commons Attribution 4.0 International License.

Pb2+ Ion Sensing by Anthracenylimino Compound and its β-Cyclodextrin Complex: A Study by Fluorescence Spectroscopy

https://doi.org/10.14233/ajchem.2019.21684
M. Sumithra
Department of Chemistry, Karunya Institute of Technology and Sciences, Coimbatore-641114, India
R. Sivaraj
Department of Chemistry, Karunya Institute of Technology and Sciences, Coimbatore-641114, India
P. Mosae Selvakumar
Department of Chemistry, Karunya Institute of Technology and Sciences, Coimbatore-641114, India
Israel V.M.V. Enoch
Department of Chemistry, Karunya Institute of Technology and Sciences, Coimbatore-641114, India; Nanotoxicology Research Lab, Department of Nanoscience, Karunya Institute of Technology and Sciences, Coimbatore-641114, India
https://orcid.org/0000-0002-8489-531X

Corresponding Author(s) : Israel V.M.V. Enoch

drisraelenoch@gmail.com

Asian Journal of Chemistry, Vol. 31 No. 5 (2019): Vol 31 Issue 5

Abstract

This paper describes the Pb2+ ion sensing of an anthacenylimino compound in the presence and absence of β-cyclodextrin in aqueous media. The chemosensor is prepared by a simple coupling reaction of an aldehyde and an amine. The compound is characterized using 1H NMR and mass spectrometric techniques. The host-guest complex of the β-cyclodextrin anthracenylimino compound is analyzed using 2D rotating-frame Overhauser effect spectroscopy and its structure is optimized. The stoichiometry of the complex is 1:1. The compound selectively binds Pb2+ ion in its free and cyclodextrin-bound forms. The ranges of sensing of the metal ion are calculated and they are similar in magnitude.

Keywords

Anthacenylimine β-Cyclodextrin Fluorescent chemosensor Host-guest complex
Sumithra, M., Sivaraj, R., Selvakumar, P. M., & Enoch, I. V. (2019). Pb2+ Ion Sensing by Anthracenylimino Compound and its β-Cyclodextrin Complex: A Study by Fluorescence Spectroscopy. Asian Journal of Chemistry, 31(5), 987–992. https://doi.org/10.14233/ajchem.2019.21684
Download Citation
Endnote/Zotero/Mendeley (RIS)
BibTeX
References
  1. C. Hou, Y. Xiong, N. Fu, C.C. Jacquot, T.C. Squier and H. Cao, Tetrahedron Lett., 52, 2692 (2011); https://doi.org/10.1016/j.tetlet.2011.03.075.
  2. D.A. Gildlow, Occup. Med., 54, 76 (2004); https://doi.org/10.1093/occmed/kqh019.
  3. H.W. Mielke and P.L. Reagan, Environ. Health Perspect., 106(Suppl.1), 217 (1998).
  4. Q. Wang, S. Zhang, H. Ge, G. Tian, N. Cao and Y. Li, Sens. Actuators B Chem., 207, 25 (2015); https://doi.org/10.1016/j.snb.2014.10.096.
  5. K. Aggarwal and J.M. Khurana, J. Lumin., 167, 146 (2015); https://doi.org/10.1016/j.jlumin.2015.06.027.
  6. Y.W. Fen, W.M.M. Yunus and N.A. Yusof, Sens. Actuators B Chem., 171-172, 287 (2012); https://doi.org/10.1016/j.snb.2012.03.070.
  7. Y. Lu, X. Li, G.K. Wang and W. Tang, Biosens. Bioelectron., 39, 231 (2013); https://doi.org/10.1016/j.bios.2012.07.045.
  8. H.G. Preuss, G. Jiang, J.W. Jones, P.O. Macarthy, P.M. Andrews and J.A. Gondal, J. Am. Coll. Nutr., 13, 578 (1994); https://doi.org/10.1080/07315724.1994.10718451.
  9. A. Skoczynska, J. Wrobel and R. Andrzejak, Toxicology, 162, 157 (2001); https://doi.org/10.1016/S0300-483X(01)00355-9.
  10. M.J.J. Ronis, T.M. Badger, S.J. Shema, P.K. Roberson and F. Shaikh, Toxicol. Appl. Pharmacol., 136, 361 (1996); https://doi.org/10.1006/taap.1996.0044.
  11. D.A. Daggett, E.F. Nuwaysir, S.A. Nelson, L.S. Wright, S.E. Kornguth and F.L. Siegel, Toxicology, 117, 61 (1997); https://doi.org/10.1016/S0300-483X(96)03555-X.
  12. K.P. Nandre, A.L. Puyad, S.V. Bhosale and S.V. Bhosale, Talanta, 130, 103 (2014); https://doi.org/10.1016/j.talanta.2014.06.064.
  13. M. Wang, F. Wang, Y. Wang, W. Zhang and X. Chen, Dyes Pigm., 120, 307 (2015); https://doi.org/10.1016/j.dyepig.2015.04.035.
  14. E.J. Antony, M. Raj, R.Q. Paulpandi, M.S. Paulraj and I.V.M.V. Enoch, J. Fluoresc., 25, 1031 (2015); https://doi.org/10.1007/s10895-015-1588-z.
  15. B.K. Datta, C. Kar, A. Basu and G. Das, Tetrahedron Lett., 54, 771 (2013); https://doi.org/10.1016/j.tetlet.2012.11.114.
  16. S. Chandrasekaran, N. Sudha, D. Premnath and I.V.M.V. Enoch, J. Biomol. Struct. Dyn., 33, 1945 (2015); https://doi.org/10.1080/07391102.2014.980323.
  17. C. Sowrirajan, S. Yousuf and I.V.M.V. Enoch, Aust. J. Chem., 67, 256 (2014); https://doi.org/10.1071/CH13364.
  18. S. Chandrasekaran, Y. Sameena and I.V.M.V. Enoch, J. Mol. Recognit., 27, 640 (2014); https://doi.org/10.1002/jmr.2387.
  19. C.R. Palem, S. Patel and V.B. Pokharkar, PDA J. Pharm. Sci. Technol., 63, 217 (2009).
  20. R.Q. Paulpandi, S. Ramasamy, M.S. Paulraj, F.G. Díaz Baños, G. Villora, J.P. Cerón-Carrasco, H. Pérez-Sánchez and I.V.M.V. Enoch, RSC Adv., 6, 15670 (2016); https://doi.org/10.1039/C6RA01202G.
  21. I.V.M.V. Enoch, R. Rajamohan and M. Swaminathan, Spectrochim. Acta A, 77, 473 (2010); https://doi.org/10.1016/j.saa.2010.06.021.
  22. Z.H. Qi, L. Zhu, H. Chen and W. Qi, J. Incl. Phenom. Molec. Recognit. Chem., 27, 279 (1997); https://doi.org/10.1023/A:1007914329584.
  23. S. Sortino, J.C. Scaiano, G.D. Guidi and S. Monti, Photochem. Photobiol., 70, 549 (1999); https://doi.org/10.1111/j.1751-1097.1999.tb08250.x.
  24. I.V.M.V. Enoch and S. Yousuf, J. Solution Chem., 42, 470 (2013); https://doi.org/10.1007/s10953-013-9965-1.
  25. I.V.M.V. Enoch and M. Swaminathan, J. Incl. Phenom. Macrocycl. Chem., 53, 149 (2005); https://doi.org/10.1007/s10847-005-2633-3.
  26. C. Dall’asta, G. Ingletto, R. Corradini, G. Galaverna and R. Marchelli, J. Incl. Phenom. Macrocycl. Chem., 45, 257 (2003); https://doi.org/10.1023/A:1024572426577.
  27. Y.-H. Chiu and J.-H. Liu, J. Polym. Sci. A, 48, 3368 (2010); https://doi.org/10.1002/pola.24121.
  28. H.A. Benesi and J.H. Hildebrand, J. Am. Chem. Soc., 71, 2703 (1949); https://doi.org/10.1021/ja01176a030.
Read More
Author biographies is not available.
Download
PDF
Statistic
Read Counter : 0 Download : 0