Kinetics of Oxidation of Cobalt(III) Bound and Unbound α-hydroxy Acids by Quinolinium Dichromate
Corresponding Author(s) : K.R. Sankaran
Asian Journal of Chemistry,
Vol. 11 No. 1 (1999): Vol 11 Issue 1
Abstract
Quinolinium dichromate (QDC) oxidizes pentaammine cobalt(III) bound and unbound mandelic and lactic acids, in the presence of 0.50 mol dm-3 HCIO4. The reaction has unit dependence on α-hydroxy acids/cobalt(III) complex and QDC. The comparative study of QDC oxidation
of cobalt(III) bound and unbound α-hydroxy acids may throw light
on the mechanistic aspects of this reaction.
Keywords
Oxidation
Cobalt(III)
?-hydroxy Acids
Quinolinium Dichromate
(1)
Sankaran, K.; Gnanasekaran, K. Kinetics of Oxidation of Cobalt(III) Bound and Unbound Α-Hydroxy Acids by Quinolinium Dichromate . ajc 2010, 11, 75-79.
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