Studies on 2N-[3-Nitrobenzalidene] Amino Pyradine Complexes of Thiorum(IV) and Dioxouranium(VI)

Abstract

Thorium(IV) and dioxouranium(VI) complexes of Schiff base 2N[
3-nitrobenzalidene] amino pyridine (3-NBAPy) derived from 3-nitrobenzaldehyde
and 2-amino pyridine having general composition ThX₄·nL
(X = NO₃^- or NCS^-, n=2; X= I^- n=4, L = 3-NBAPy; X=ClO₄^-, n=6,
L = 3-NBAPy) and UO₂X₂·nL (X = I^-, NCS^-, NO₃^- or CH₃COO^-, n = 2;
X = ClO₄^-, n = 4, L = 3-NBAPy) have been synthesized and characterized
by molecular weight, conductance, IR and electronic spectral measurements.
XRD for two of the representative samples has been done successfully.