Mixed Ligand Complexes of Alkali Metal Salts of Organic Acids with o-Amino Thiophenol

Abstract

Complexes of the type ML·HL' have been synthesised and characterised,
where M = Li, Na or K, HL' = o-amino thiophenol,
L = deprotonated o-nitro phenol, 2,4-dinitrophenol, 1-nitroso-2-
naphthol and 8-hydroxy quinoline. All the complexes have been
found to be four-coordinated in which ligand o-amino thiophenol
is coordinated through N-atom of amino group and S-atom of the
thiol group forming five-membered stable chelation.