Kinetics of Oxidant of Hexahydroxycyclohexane by Os(VIII) Continuously Regenerated by Hexacyanoferrate(III) ions
Corresponding Author(s) : S.P.S. Mehta
Asian Journal of Chemistry,
Vol. 12 No. 4 (2000): Vol 12 Issue 4
Abstract
The kinetics of oxidation of hexahydroxycyclohexane (mesoform)
by alkaline Os(VIII) which was continuously regenerated by
Fe(CN)63- was studied in the 1.0 M-10.0 M [OH- ] and 293 K-313 K
temperature range. The rate of the reaction was found to be one
each with respect to Os(VIII) and Fe(CN)63-. Suitable mechanism
consistent with the observed kinetics has been proposed.
Keywords
Kinetics
Oxidant
Hexahydroxycyclohexane
Os(VIII)
Hexacyanoferrate(III) ions
(1)
Mehta, S. Kinetics of Oxidant of Hexahydroxycyclohexane by Os(VIII) Continuously Regenerated by Hexacyanoferrate(III) Ions. ajc 2010, 12, 1041-1046.
Download Citation
Endnote/Zotero/Mendeley (RIS)BibTeX