Synthesis, 2D NMR, Electrochemistry and Luminescence Ruthenium(II) Complexes with 2,2'-Bipyridine and 5-(ω-Bromoalkylamido)-1,10-phenanthroline
Peng Wang
Laboratory of Electroanalytical Chemistry, Changchun Institute of Applied Chemistry Chinese Academy of Sciences, Changchun, 130022, P.R. China
Xiaoyan Jing
Department of Chemical Engineering Harbin Engineering University, Harbin, 150001, P.R. China
Xiangping Wang
Laboratory of Electroanalytical Chemistry, Changchun Institute of Applied Chemistry Chinese Academy of Sciences, Changchun, 130022, P.R. China ; Department of Chemical Engineering Harbin Engineering University, Harbin, 150001, P.R. China
Jun Wang
Department of Chemical Engineering Harbin Engineering University, Harbin, 150001, P.R. China
Guoyi Zhu
Laboratory of Electroanalytical Chemistry, Changchun Institute of Applied Chemistry Chinese Academy of Sciences, Changchun, 130022, P.R. China
Corresponding Author(s) : Xiaoyan Jing
Asian Journal of Chemistry,
Vol. 12 No. 3 (2000): Vol 12 Issue 3
The efficient synthesis of 5-(5-bromovaleramido)-1, 10-phenan· throline, 5-(6-bromohexanamido)-1,10-phenanthroline, and 5-(11-bromoundecanamido)- 1,10-phenanthroline are described, which reacted with cis-Ru(bpy)2CI2·2H2O and sodium hexafluorophosphate to form Ru(bpy)2[phen-NHCO(CH2)nBr](PF6)2 (n = 4, 5 or 10; phen = 1,10- phenanthroline). The intricate 1H NMR spectra at low field of these complexes were completely assigned in virtue of 1H-1H COSY technique. Cyclic voltammetry was used to study electrochemical behaviours of these complexes, and their luminescent properties were investigated with fluorescent spectra.
Wang, P., Jing, X., Wang, X., Wang, J., & Zhu, G. (2010). Synthesis, 2D NMR, Electrochemistry and Luminescence Ruthenium(II) Complexes with 2,2’-Bipyridine and 5-(ω-Bromoalkylamido)-1,10-phenanthroline. Asian Journal of Chemistry, 12(3), 643–649. Retrieved from https://asianpubs.org/index.php/ajchem/article/view/23036
