Polarographic Studies of Mixed Ligand Complexes Of Copper Cadaverine with Some Carboxylic Acids
Corresponding Author(s) : S.K. Mukerji
Asian Journal of Chemistry,
Vol. 12 No. 2 (2000): Vol 12 Issue 2
Abstract
Mixed ligand complexes of Cu(II) with cadaverine and carboxylic
acids including adipic acid, succinic acid, maleic acid,
malonic acid and phthalic acid have been studied polarographically.
Formation constants of these complexes have been evaluated using
McMaster and Schaap technique. The log K values for Cu-Cdv-Phth,
Cu-Cdv-Mal, Cu-Cdv-Malo, Cu-Cdv-Succ and Cu-Cdv-Adp
systems are -3.02, -3.50, -3.11, -3.67 and -2.51, respectively. The
pH's of the solutions were kept at 7.9, 8.6, 8.2, 8.3 and 8.2 for the Malo-
Cdv, ,Mal-Cdv, Adp-Cdv, Succ-Cdv, Phth-Cdv systems,
respectively.
Keywords
Polarographic Study
Mixed Ligand Complexes
Copper Cadaverine
Carboxylic Acids
Kumar Lohiya, R., Lal Prathar, P., Singh, R., & Mukerji, S. (2010). Polarographic Studies of Mixed Ligand Complexes Of Copper Cadaverine with Some Carboxylic Acids . Asian Journal of Chemistry, 12(2), 565–573. Retrieved from https://asianpubs.org/index.php/ajchem/article/view/22998
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