Reaction of Nitrilimines with Aromatic and Heterocyclic Ketoximes, Part 3: Synthesis of Substituted 1,2,4-Triazoles and 1,2,4,8-Tetraazaspiro[4,5]dec-2-enes
Corresponding Author(s) : Abdel-Rahman S. Ferwanah
Asian Journal of Chemistry,
Vol. 13 No. 3 (2001): Vol 13 Issue 3
Abstract
Nitrilimines (2a-g) react with acetophenone oxime (3) to afford 3-acyl-1-
aryl-4,5-dihydro-5-methyl-5-phenyl-1H-1 ,2,4-triazoles (4a-g). Similarly,
the reaction of nitrilimines (2) with 1-methyl-4-piperidone oxime (6)
gives 3-acyl-1-aryl-8-methyl-1,2,4,8-tetraazaspiro[ 4,5]dec-2-enes (7).
Spectral data of the title compounds are discussed.
Keywords
Nitrilimines
Aromatic
Heterocyclic Ketoximes
1,2,4-Triazoles
1,2,4,8-Tetraazaspiro[4,5]dec-2-enes
S. Ferwanah, A.-R., M. Awadallah, A., & A. Khafaja, N. (2010). Reaction of Nitrilimines with Aromatic and Heterocyclic Ketoximes, Part 3: Synthesis of Substituted 1,2,4-Triazoles and 1,2,4,8-Tetraazaspiro[4,5]dec-2-enes. Asian Journal of Chemistry, 13(3), 1203–1209. Retrieved from https://asianpubs.org/index.php/ajchem/article/view/22761
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