Spectrochemical, EXAFS and XANES Studies of Cu(II), Ni(II) and Co(II) Complexes of m-Mercaptoacetamido Phenol
Corresponding Author(s) : V.W. Bhagwat
Asian Journal of Chemistry,
Vol. 13 No. 1 (2001): Vol 13 Issue 1
Abstract
Complexes of Cu(II), Ni(II) and Co(II) with m-mercaptoacetamido
phenol (m-MAP) have been synthesised. Analytical studies show a 1 : 2
(M : L) stoichiometry for Ni(II) and Co(II) complexes while for copper
the stoichiometry is found to be 1 : 1 and copper is present in the complex
in Cu(I) state. The electronic spectral studies suggest octahedral geometry
for Co(II) and Ni(II) complexes and is supported by EXAFS and XANES.
Infrared studies indicate bonding through —C=O and —SH group.
Keywords
EXAFS
XANES
Ni(II)
Co(II)
Phenol
Cu(II)
Bhagwat, V., Nahar, P., & Mishra, A. (2010). Spectrochemical, EXAFS and XANES Studies of Cu(II), Ni(II) and Co(II) Complexes of m-Mercaptoacetamido Phenol. Asian Journal of Chemistry, 13(1), 339–340. Retrieved from https://asianpubs.org/index.php/ajchem/article/view/22578
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