Photochemical Studies of Bipyridyl/γ-Picoline Adduct of bis-(4,5-Dimethyl-1,3,2-dioxaphospholane-2-thione-2-thiolato) nickel (II) under Photoirradiation, Part-III†
Corresponding Author(s) : C.P. Bhasin
ngu_cc@wilnetonline.net
Asian Journal of Chemistry,
Vol. 14 No. 3 (2002): Vol 14 Issue 3
Abstract
On irradiation with visible light six coordinated octahedral bipyridyl adduct of nickel(II) bis-(O,O-butylene dithiophosphate) is converted into five coordinated trigonal-bipyramidal complex. Four coordinated nickel(II) bis-(O,O-butylene dithiophosphate) on reaction with bipyridyl under photo-irradiation forms five coordinated
complex again. In contrast to the above, four coordinated
bis-(O,O-butylene dithiophosphate) nickel(II) on reaction with
γ-picoline under photoirradiation forms six coordinated complex.
Keywords
Photochemical
Adduct
Ni(II) Complex
Bipyridyl/γ-Picoline
Bhasin, C., K.A. Parmar, M., & Dave, R. (2010). Photochemical Studies of Bipyridyl/γ-Picoline Adduct of bis-(4,5-Dimethyl-1,3,2-dioxaphospholane-2-thione-2-thiolato) nickel (II) under Photoirradiation, Part-III† . Asian Journal of Chemistry, 14(3), 1601–1606. Retrieved from https://asianpubs.org/index.php/ajchem/article/view/22445
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