Kinetic Studies on the Reaction between Benzyl/Phenacyl Chloride and N,N-Dimethylaniline in Acetone-Water Mixed Solvents
Corresponding Author(s) : M. Nallu
Asian Journal of Chemistry,
Vol. 14 No. 3 (2002): Vol 14 Issue 3
Abstract
Rate constants (k1) for the reaction between benzyl chloride (BC)/phenacyl chloride (PC) and N,N-dimethylaniline (DMA) have been determined conductometrically under pseudo-first-order conditions. Second order rate constants (k2) were evaluated in the usual way. The effect of electron withdrawing —CO— group α-to chlorine
is not felt on the values of k2(pc + DMA). The marked effect of
acetone-water solvent composition on the rate is known from correlation
technique with log k2(BC/PC + DMA) with Grunwald-Winsteins
(Y) and Kosowar (Z) of solvent polarity parameters.
Keywords
Kinetics
Reaction
Benzyl Chloride
Phenacyl Chloride
Solvents
N,N-Dimethylaniline
Nallu, M., & Kanagadurgadevi, G. (2010). Kinetic Studies on the Reaction between Benzyl/Phenacyl Chloride and N,N-Dimethylaniline in Acetone-Water Mixed Solvents . Asian Journal of Chemistry, 14(3), 1320–1324. Retrieved from https://asianpubs.org/index.php/ajchem/article/view/22401
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