Micellar Effect on the Reaction of Acid Green-16 with K2S2O8 Ion: Influence of Salts and Organic Solvents

Hitendra M. Joshi; T.N. Nagar

Issue

Vol. 14 No. 3 (2002): Vol 14 Issue 3

Issue Published : October 1, 2002

Micellar Effect on the Reaction of Acid Green-16 with K2S2O8 Ion: Influence of Salts and Organic Solvents

Hitendra M. Joshi

Department of Chemistry, South Gujarat University, Surat -95 007, India

T.N. Nagar

Department of Chemistry, South Gujarat University, Surat -95 007, India

Corresponding Author(s) : Hitendra M. Joshi

Asian Journal of Chemistry, Vol. 14 No. 3 (2002): Vol 14 Issue 3
Article Published : March 30, 2010

Abstract

Cationic micelles of cetyl trimethyl ammonium bromide (C₁₆TABr) increase the rate of reaction of triphenylmethyl carbonium ions with S₂O₈^2– ion whereas the anionic micelles of sodium dodecyl sulphate (SDS) inhibit this rate. The addition of monohydric alcohols, viz., n-butanol, ethanol and solvents like acetone and dimethylformamide decreases the cationic micellar catalysed rate, while on the other hand increases the anionic micellar inhibited rate. The influence of electrolytes in the presence of C₁₆TABr has also been analysed.

Keywords

Micellar Effect Acid Green-16 Potassium peroxy disulphate

M. Joshi, H., & Nagar, T. (2010). Micellar Effect on the Reaction of Acid Green-16 with K2S2O8 Ion: Influence of Salts and Organic Solvents. Asian Journal of Chemistry, 14(3), 1265–1269. Retrieved from https://asianpubs.org/index.php/ajchem/article/view/22391

Issue

Vol. 14 No. 3 (2002): Vol 14 Issue 3

Micellar Effect on the Reaction of Acid Green-16 with K2S2O8 Ion: Influence of Salts and Organic Solvents

Corresponding Author(s) : Hitendra M. Joshi

Abstract

Keywords

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