Spectrochemical, EXAFS and Studies of Co(II), Ni(II) and Cu(II) Complexes of Thioglycolanalide

V.W. Bhagwat; P.C. Nahar; Ashutosh Mishra; Ajit Choube

Issue

Vol. 14 No. 2 (2002): Vol 14 Issue 2

Issue Published : June 10, 2002

Spectrochemical, EXAFS and Studies of Co(II), Ni(II) and Cu(II) Complexes of Thioglycolanalide

V.W. Bhagwat

School of Studies in Chemistry, Vikram University, Ujjain-456 010, India

P.C. Nahar

School of Studies in Chemistry, Vikram University, Ujjain-456 010, India

Ashutosh Mishra

School of Studies in Chemistry, Vikram University, Ujjain-456 010, India

Ajit Choube

School of Studies in Chemistry, Vikram University, Ujjain-456 010, India

Corresponding Author(s) : V.W. Bhagwat

Asian Journal of Chemistry, Vol. 14 No. 2 (2002): Vol 14 Issue 2
Article Published : March 30, 2010

Abstract

Complexes of Co(II), Ni(II) and Cu(II) with thioglycolanalide (TGA) have been synthesized. Analytical studies show a 1:2 (M:L) stoichiometry for Ni(II) and Co(II) complexes while for copper the stoichiometry is found to be 1:1 and copper is present in the complex in Cu(I) state. The electronic spectral studies suggest octahedral
geometry for Co(II) and Ni(II) complexes and is supported
by EXAFS and XANES. Infrared studies indicate bonding through
>C=O and —SH groups.

Keywords

Spectrochemical TGA EXAFS XANES Metal complexes

Bhagwat, V., Nahar, P., Mishra, A., & Choube, A. (2010). Spectrochemical, EXAFS and Studies of Co(II), Ni(II) and Cu(II) Complexes of Thioglycolanalide . Asian Journal of Chemistry, 14(2), 1041–1043. Retrieved from https://asianpubs.org/index.php/ajchem/article/view/22258

Issue

Vol. 14 No. 2 (2002): Vol 14 Issue 2

Spectrochemical, EXAFS and Studies of Co(II), Ni(II) and Cu(II) Complexes of Thioglycolanalide

Corresponding Author(s) : V.W. Bhagwat

Abstract

Keywords

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