Intermolecular Inter-ligand Interaction in Mixed Ligand Complexes of Lanthanides(III) Involving Histidine and Some Amino Acids
Corresponding Author(s) : Vivek Tiwari
Asian Journal of Chemistry,
Vol. 15 No. 3 (2003): Vol 15 Issue 3
Abstract
The formation constant studies on binary and mixed ligand complexes
of Pr(III) and Nd(III) involving histidine (hist) as primary
ligand and α-alanine ( α-ala), valine (val) or leucine (leu) as secondary
ligands have been undertaken to evaluate the extra-stablization
in the mixed ligand complexes due to possible occurrence of
intramolecular inter-ligand interaction. Stability quantifying parameters
( Δlog k and ΔΔ log k) indicate significant inter-ligand interaction.
Keywords
Intermolecular
Inter-ligand
Interaction
Mixed ligand complexes
Lanthanides
Histidine
Amino acids
Valine
Leucine
α-alanine
Tiwari, V., & Singhai, R. (2010). Intermolecular Inter-ligand Interaction in Mixed Ligand Complexes of Lanthanides(III) Involving Histidine and Some Amino Acids . Asian Journal of Chemistry, 15(3), 1814–1816. Retrieved from https://asianpubs.org/index.php/ajchem/article/view/21910
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