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Vol. 15 No. 2 (2003): Vol 15 Issue 2

Generation and Characterization of New Oxovanadium Complexes on Polymer Support

Sheela Chacko
Research and P.G. Department of Chemistry, St. Thomas College, Pala, India
Tessymol Mathew
Research and P.G. Department of Chemistry, St. Thomas College, Pala, India
M. Padmanabhan
Research and P.G. Department of Chemistry, St. Thomas College, Pala, India
Sunny Kuriakose
Research and P.G. Department of Chemistry, St. Thomas College, Pala, India

Corresponding Author(s) : Sunny Kuriakose

Asian Journal of Chemistry, Vol. 15 No. 2 (2003): Vol 15 Issue 2

Abstract

2 Per cent divinyl benzene (DVB) crosslinked polystyrene support was
synthesised and functionalised to get chloromethyl polystyrene. Polymeric
ligands were prepared by anchoring ligand systems like Schiff base, ethylene
diamine and dithiocarbamate on to the polymer backbone. A series
of oxovanadium complexes were generated on the polymer support by
polymer-analogous complexation reactions. Polymeric oxovanadium complexes
containing S2O2, N2O2 and NO3 chromophores were analysed by
chemical and spectroscopic methods. Important spectral results from UV-Vis,
IR and EPR analysis are discussed in detail. The results best explain
the bonding pattern and stereochemistry of the complexes.

Keywords

Polymer Ligand Complexes Oxovanadium EPR spectra
Chacko, S., Mathew, T., Padmanabhan, M., & Kuriakose, S. (2010). Generation and Characterization of New Oxovanadium Complexes on Polymer Support . Asian Journal of Chemistry, 15(2), 825–832. Retrieved from https://asianpubs.org/index.php/ajchem/article/view/21706
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