Synthesis of New 2,3-Disubstituted Quinoxalines from 4,4-Substituted Chalcones
Corresponding Author(s) : A.Y. Deshmukh
Asian Journal of Chemistry,
Vol. 15 No. 2 (2003): Vol 15 Issue 2
Abstract
4'-Chlorochalcone (Ia), 4'-chloro-4-methoxychalcone (Ib), 4'nitrochalcone (Ic) and 4' -nitro-4-methoxychalcone (Id) react with bromine in acetic acid to give chalcone dibromides (lIa-d). The chalcone dibromides (IIa-d) condense with benzene 1,2-diamine (BDA) in presence of few drops of concentrated H2SO4 in methanel medium to affords 2,3-disubstituted quinoxalines (IIIa-d). The structures of these compounds were confirmed by analytical and spectral data.
Keywords
Synthesis
2,3-Disubstituted Quinoxalines
4,4-Substituted Chalcones
Deshmukh, A., Raghuwanshi, P., & Doshi, A. (2010). Synthesis of New 2,3-Disubstituted Quinoxalines from 4,4-Substituted Chalcones . Asian Journal of Chemistry, 15(2), 821–824. Retrieved from https://asianpubs.org/index.php/ajchem/article/view/21705
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